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Published TCIMAIL newest issue No.197
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CAS RN: 198-55-0 | Product Number: P1629
Perylene (purified by sublimation)
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Purity: >99.0%(GC)
Synonyms:
- Dibenz[de,kl]anthracene (purified by sublimation)
- Peri-dinaphthalene (purified by sublimation)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
£58.00
|
1 | 16 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | P1629 |
| Purity / Analysis Method | >99.0%(GC) |
| Molecular Formula / Molecular Weight | C__2__0H__1__2 = 252.32 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 198-55-0 |
| Reaxys Registry Number | 1911335 |
| PubChem Substance ID | 87558356 |
| SDBS (AIST Spectral DB) | 3151 |
| Merck Index (14) | 7184 |
| MDL Number | MFCD00004142 |
Specifications
| Appearance | Light yellow to Brown powder to crystaline |
| Purity(GC) | min. 99.0 % |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 278 °C |
GHS
Related Laws:
| EC Number | 205-900-9 |
| RTECS# | SE3794000 |
Transport Information:
| HS Number | 2902900000 |
Application
CHF2-sulfonium salt for Photo-catalytic Difluoromethylations
A Schlenk tube is charged with an acetonitrile (5.0 mL) solution of an aromatic alkene (0.250 mmol), D5630 (190 mg, 0.500 mmol), perylene (3.2 mg, 0.0127 mmol) and water (4.5 mg, 0.250 mmol) under a nitrogen atmosphere. The mixture is degassed by freeze-pump-thaw cycles. The Schlenk tube is placed at 2－3 cm away from blue LED lamps (λ = 425 ± 15 nm) in a water bath. The mixture is stirred for 6－12 h at room temperature under visible light irradiation. After the reaction, water (15 mL) is added and resulting suspension is extracted with dichloromethane (15 mL × 3). The combined organic layer is dried over sodium sulfate , and concentrated under reduced pressure. The purification by column-chromatography and repreciptitation affords the desired products.
References
- Metal-free Di- and Tri-fluoromethylation of Alkenes Realized by Visible-light-induced Perylene Photoredox Catalysis
Application
Organic Electroluminescent Material
References
- Electroluminescence in organic films with three-layer structure
- C. Adachi, S. Tokito, T. Tsutsui, S. Saito, Jpn. J. Appl. Phys. Part 2 1988, 27, L269.
- Electroluminescence of epitaxial perylene films
- Reduction of molecular aggregation and its application to the high-performance blue perylene-doped organic electroluminescent device
Application
Organic Semiconductor Material
References
- Energy gaps in organic semiconductors derived from electrochemical data
- Epitaxial growth of a crystalline organic semiconductor:? Perylene/Cu{110}
- Organic field-effect transistors using perylene
PubMed Literature
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