CAS RN: 50525-27-4 | 产品编码: T1655

Tris(2,2'-bipyridyl)ruthenium(II) Chloride Hexahydrate

纯度/分析方法: >98.0%(T)

别名：

氯化三(2,2'-联吡啶)钌(II) 六水合物
六水合三(2,2-联吡啶)氯化钌(II) 六水合物
Dichlorotris(2,2'-bipyridyl)ruthenium(II) Hexahydrate
Tris(2,2'-bipyridyl)dichlororuthenium(II) Hexahydrate
Ru(bpy)₃Cl₂ Hexahydrate

产品文档：

规格	单价	上海	天津	日本*	库存详情
250MG	¥390.00	3	从上海仓库发货	请联系我们	查询
1G	¥1,290.00	1	2	≥100	查询
5G	¥4,090.00	2	1	36	查询

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基本信息

产品编码	T1655
纯度/分析方法	>98.0%(T)
分子式/分子量	C__3__0H__2__4Cl__2N__6Ru·6H__2O = 748.62
外观与形状（20°C）	固体
储存温度	室温 (15°C以下阴凉干燥处)
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气
包装和容器	1G-带有塑料内管的玻璃瓶（查看图片）, 250MG-带有塑料内管的玻璃瓶（查看图片）
CAS RN	50525-27-4
Reaxys-RN	14615736
PubChem物质ID	87577396
MDL编号	MFCD00149670

技术规格和文件

技术规格

Appearance	Orange to Amber to Dark red powder to crystal
Purity(Precipitation Titration)	min. 98.0 %
Water	12.0 to 15.0 %

物性（参考值）

水溶性

可溶

安全和法规

GHS

相关法规

RTECS#	VM2730000
新化学物质备案回执号	B1A232215734

运输信息

监管条件代码(*)

应用实例・文献

应用

TCI Practical Example: Arylation of N-Heteroarene Using a Photoredox Catalyst

Used Chemicals

Procedure: Ru(bpy)₃Cl₂･6H₂O (80.1 mg, 0.125 mmol, 2.5 mol%), caffeine (9.71 g, 50.0 mmol, 10 eq.), 4-methoxybenzenediazonium tetrafluoroborate (1.11 g, 5.00 mmol, 1.0 eq.) and formic acid (25 mL) were added to a 100 mL four-necked round bottomed flask at room temperature. The mixture was placed at a distance of 2-3 cm from Blue LED lamps. The brown solution was stirred at rt under visible light irradiation. After 14 hours of irradiation, 5% sodium bicarbonate and dichloromethane were added. The organic layer was washed with brine. Organic layer was dried over Na₂SO₄ and concentrated under reduced pressure to afford the crude product as a red solid (8.20 g), which was purified by column chromatography on silica gel (hexane:ethyl acetate = 80:20 - 34:66) to afford compound 1 as a pale red solid (632 mg, y. 42 %).

Experimenter’s Comments: The flask was irradiated with 40 W blue LED lamps (3 cm away, with cooling fans to keep the reaction at room temperature).
The reaction mixture was monitored by ¹H NMR.

Analytical Data（Compound 1）

¹H NMR (400 MHz, CDCl₃); δ 7.62 (d, J = 8.7 Hz, 2H), 7.01 (d, J = 8.7 Hz, 2H), 4.02 (s, 3H), 3.86 (s, 3H), 3.61 (s, 3H), 3.41 (s, 3H).

¹³C NMR (101 MHz, CDCl₃); δ 161.1, 155.5, 152.1, 151.7, 148.2, 130.6, 120.5, 114.3, 108.2, 55.4, 33.9, 29.8, 27.9.

Lead Reference