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CAS RN: 198-55-0 | Product Number: P0078
Perylene
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Purity: >98.0%(GC)
Synonyms:
- Dibenz[de,kl]anthracene
- Peri-dinaphthalene
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$36.00
|
Contact Us | 1 | 5 |
|
| 5G |
$108.00
|
28 | 1 | ≥60 |
|
| 25G |
$396.00
|
2 | 1 | 23 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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| Product Number | P0078 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__2__0H__1__2 = 252.32 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 198-55-0 |
| Reaxys Registry Number | 1911335 |
| PubChem Substance ID | 87574341 |
| SDBS (AIST Spectral DB) | 3151 |
| Merck Index (14) | 7184 |
| MDL Number | MFCD00004142 |
Specifications
| Appearance | Light yellow to Brown powder to crystal |
| Purity(GC) | min. 98.0 % |
Properties (reference)
| Melting Point | 279 °C |
GHS
Related Laws:
| RTECS# | SE3794000 |
Transport Information:
| HS Number | 2933.99.7900 |
Application
Organic Photocatalysts Applied to Metal-Free Atom Transfer Radical Polymerization
References
- Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization
- Metal-Free Atom Transfer Radical Polymerization
- Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light
- Metal-free photoinduced electron transfer–atom transfer radical polymerization (PET–ATRP) via a visible light organic photocatalyst
- Phenyl Benzo[b]phenothiazine as a Visible Light Photoredox Catalyst for Metal-Free Atom Transfer Radical Polymerization
Application
CHF2-sulfonium salt for Photo-catalytic Difluoromethylations
A Schlenk tube is charged with an acetonitrile (5.0 mL) solution of an aromatic alkene (0.250 mmol), D5630 (190 mg, 0.500 mmol), perylene (3.2 mg, 0.0127 mmol) and water (4.5 mg, 0.250 mmol) under a nitrogen atmosphere. The mixture is degassed by freeze-pump-thaw cycles. The Schlenk tube is placed at 2−3 cm away from blue LED lamps (λ = 425 ± 15 nm) in a water bath. The mixture is stirred for 6−12 h at room temperature under visible light irradiation. After the reaction, water (15 mL) is added and resulting suspension is extracted with dichloromethane (15 mL × 3). The combined organic layer is dried over sodium sulfate , and concentrated under reduced pressure. The purification by column-chromatography and repreciptitation affords the desired products.
References
- Metal-free Di- and Tri-fluoromethylation of Alkenes Realized by Visible-light-induced Perylene Photoredox Catalysis
PubMed Literature
Articles/Brochures
Product Documents (Note: Some products will not have analytical charts available.)
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Specifications
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Other Documents
Related Products
Perylene (purified by sublimation)
| Product # | P1629 |
| CAS RN | 198-55-0 |
| Purity / Analysis Method: | >99.0%(GC) |