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CAS RN: 1662-01-7 | Product Number: D0905
Bathophenanthroline
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Purity: >99.0%(T)
Synonyms:
- 4,7-Diphenyl-1,10-phenanthroline
- Bphen
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$91.00
|
1 | 1 | ≥40 |
|
| 5G |
$287.00
|
Contact Us | Contact Us | 19 |
|
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| Product Number | D0905 |
| Purity / Analysis Method | >99.0%(T) |
| Molecular Formula / Molecular Weight | C__2__4H__1__6N__2 = 332.41 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 1662-01-7 |
| Reaxys Registry Number | 261048 |
| PubChem Substance ID | 87567505 |
| SDBS (AIST Spectral DB) | 3200 |
| MDL Number | MFCD00004976 |
Specifications
| Appearance | White to Orange to Green powder to crystal |
| Purity(Nonaqueous Titration) | min. 99.0 % |
| Purity(HPLC) | min. 98.0 area% |
| Melting point | 218.0 to 221.0 °C |
| Sensitiveness | Abs min.0.36(near 533nm) in the presence of Fe(1 ppm) |
Properties (reference)
| Melting Point | 221 °C |
| Solubility in water | Slightly soluble |
| Solubility (soluble in) | Ethanol, Acetone, Benzene |
GHS
Related Laws:
| RTECS# | SF8427000 |
Transport Information:
| HS Number | 2933.99.7900 |
Application
Arylation via C-H Activation using an Organocatalyst
Typical Procedure: A mixture of bathophenanthroline (7.6 mg, 23 µmol), sodium tert-butoxide (43.3 mg, 0.451 mmol), 4-iodotoluene (48.6 mg, 0.223 mmol) and benzene (2.4 mL, 27 mmol) in a 35 mL oven-dried pressure-resistant tube is stirred at 155 °C for 6 h. After cooling, the reaction mixture is quenched with a 1 N HCl aqueous solution (4 mL) and extracted with Et2O (10 mL × 3). The combined organic layer is dried over MgSO4, filtered, and concentrated in vacuo. Purification with PTLC (silica gel, hexane : EtOAc = 20 : 1) gives the product (28.4 mg, Y. 76%).
References
Application
Iron-catalyzed direct arylation of benzenes
Typical procedure: To a vial is added Fe(OAc)2 (4.3 mg), bathophenanthroline (16.6 mg), and KOt-Bu (112 mg). To the vial is then added iodobenzene (102 mg) and benzene (3.9 g). The reaction was stirred vigorously at room temperature for 20 min and then at 80 °C for 20 h. Following cooling, 2 mL of CH2Cl2/hexanes (1:1) is added, and the solution is filtered through silica pad. The pad then rinsed with 15 mL of CH2Cl2/hexanes (1:1). The combined solution is concentrated and the crude mixture is purified by column chromatography (eluent: hexanes) to give biphenyl (68.6 mg, 89 %) as a white solid.
References
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] Copper/photoredox-catalyzed Decarboxylative sp3 C–N Coupling Reaction of N-Heteroaromatics[Research Articles] Arylation via C-H Activation using an Organocatalyst
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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Other Documents
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