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CAS RN: 19978-61-1 | Product Number: B2016
[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride
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![[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "[1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride")
Purity: >98.0%(T)
Synonyms:
- [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II)
- Dichloro[1,2-bis(diphenylphosphino)ethane]palladium(II)
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
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|---|---|---|---|---|---|
| 1G |
A$183.00
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15 | 16 | Contact Us | |
| 5G |
A$582.00
|
8 | 21 | Contact Us |
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| Product Number | B2016 |
| Purity / Analysis Method | >98.0%(T) |
| Molecular Formula / Molecular Weight | C__2__6H__2__4Cl__2P__2Pd = 575.75 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 19978-61-1 |
| Reaxys Registry Number | 14861078 |
| PubChem Substance ID | 87564896 |
| SDBS (AIST Spectral DB) | 50712 |
| MDL Number | MFCD00015702 |
Specifications
| Appearance | White to Yellow to Green powder to crystal |
| Purity(Chelometric Titration) | min. 98.0 % |
| Purity(Argentometric Titration) | min. 98.0 % |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. |
Related Laws:
Transport Information:
| H.S.code* | 2843.90-000 |
Application
Palladium-catalyzed Cyanation of Aryl Halides
Typical Procedure:
Under air, a Schlenk tube is charged with CuSCN (60.8 mg, 0.5 mmol), aryl iodides (0.7 mmol, 1.25 eq.), PdCl2(dppe) (2.9 mg, 1 mol%), HCOONa (102.0 mg, 3.0 eq.), HCOOH (2.0 µL, 10 mol%), and DMSO/H2O = 8 : 1 (3.0 mL). The mixture is stirred at 100 °C (oil bath temperature) for 36 h, or until complete consumption of starting material as monitored by TLC or GC－MS analysis. The reaction mixture is allowed to cool to room temperature, poured into brine (20 mL), and extracted with EtOAc (4 × 5 mL). The combined organic layers are washed with water and dried over MgSO4, and the solvents are removed under vacuum. The residue is purified by flash column chromatography (petroleum ether―ethyl acetate) to afford the desired product.
Under air, a Schlenk tube is charged with CuSCN (60.8 mg, 0.5 mmol), aryl iodides (0.7 mmol, 1.25 eq.), PdCl2(dppe) (2.9 mg, 1 mol%), HCOONa (102.0 mg, 3.0 eq.), HCOOH (2.0 µL, 10 mol%), and DMSO/H2O = 8 : 1 (3.0 mL). The mixture is stirred at 100 °C (oil bath temperature) for 36 h, or until complete consumption of starting material as monitored by TLC or GC－MS analysis. The reaction mixture is allowed to cool to room temperature, poured into brine (20 mL), and extracted with EtOAc (4 × 5 mL). The combined organic layers are washed with water and dried over MgSO4, and the solvents are removed under vacuum. The residue is purified by flash column chromatography (petroleum ether―ethyl acetate) to afford the desired product.
References
PubMed Literature
Articles/Brochures
TCIMAIL
[TCIMAIL No.103] Palladium Catalysts[Research Articles] Palladium-catalyzed Cyanation of Aryl Halides
Product Documents (Note: Some products will not have analytical charts available.)
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Specifications
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