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Published TCIMAIL newest issue No.198 | Product Document Searching Made Easy by 2D Code! | TCI Materials Science News March 2025 | [TCIPracticalExample] Synthesis of a Silyl Enol Ether Using... | Various analytical charts can be searched on each product detail page and Product Document Search (The kinds of analytical charts differ by product)

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CAS RN: 1414707-08-6 | Product Number: A3009

AquaMet

Purity: >95.0%(HPLC)

Synonyms:

[1,3-Bis(2,4,6-trimethylphenyl)-4-[(4-ethyl-4-methylpiperazinium-1-yl)methyl]-2-imidazolidinylidene]dichloro(2-isopropoxybenzylidene)ruthenium(II) Chloride

Product Documents:

Size	Unit Price	Same Day	2-3 Business Days	Other Lead Time	Shipping Information
100MG	A$402.00	1	1	Contact Us	Shipping Simulation
500MG	A$1,170.00	1	6	Contact Us	Shipping Simulation

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* ChemSupply Australia Pty Ltd (Phone: 08-8440-2000 / email: sales@chemsupply.com.au)

Supplemental Product Information:

Sold in collaboration with Apeiron Synthesis.
PCT/EP2013/053967

General Information plus

Product Number	A3009
Purity / Analysis Method	>95.0%(HPLC)
Molecular Formula / Molecular Weight	C₃₉H₅₅Cl₃N₄ORu = 803.32
Physical State (20 deg.C)	Solid
Storage Temperature	Refrigerated (0-10°C)
Store Under Inert Gas	Store under inert gas
Condition to Avoid	Hygroscopic,Heat Sensitive
Packaging and Container	100MG-Glass Bottle with Plastic Insert (View image), 500MG-Glass Bottle with Plastic Insert (View image)
CAS RN	1414707-08-6
Reaxys Registry Number	27464286
PubChem Substance ID	354334182
MDL Number	MFCD28411647

Specifications & Properties plus

Safety & Regulations plus

Applications & Literature plus

Application

TCI Practical Example: Olefin Metathesis

Used Chemicals

Procedure: In a 200 mL two necked round bottomed flask, AquaMet (50 mg, 52 μmol) was added, and purged with N₂. Dichloromethane (100 mL) was charged in the flask, and diethyl diallylmalonate (500 mg, 2.08 mmol) in dichloromethane (20 mL) was added dropwise and the mixture was stirred at room temperature for 6 h. The solvent was removed under reduced pressure and the residue was purified by silica-gel column chromatography (hexane : EtOAc = 1 : 1) to give diethyl cyclopent-3-ene-1,1-dicarboxylate as a pale yellow oil (430 mg, 98%).

Experimenter's Comments: The reaction mixture was monitored by NMR.

Analytical Data（Diethyl cyclopent-3-ene-1,1-dicarboxylate）: ¹H NMR (400 MHz, CDCl₃); δ 5.61 (s, 2H), 4.20 (q, J = 8.0 Hz, 4H), 3.01 (s, 4H), 1.25 (t, J = 8.0 Hz, 6H).

Lead Reference

Nitro-Substituted Hoveyda−Grubbs Ruthenium Carbenes: Enhancement of Catalyst Activity through Electronic Activation
- A. Michrowska, R. Bujok, S. Harutyunyan, V. Sashuk, G. Dolgonos, K. Grela, J. Am. Chem. Soc. 2004, 126, 9318.

Application

Metathesis Catalyst Usable in Water Media

Flask equipped with a magnetic stirring bar is charged with Z-olefin (8.7 mg, 0.15 mmol) and non-degassed D₂O (1.5 ml). Next to this solution AquaMet (0.6 mg, 0.75 µmol) is added. Reaction mixture is stirred at 25 °C for 1.1 h. Next 0.7 ml of reaction mixture is transferred to an NMR tube. Yield of a product (71%) is determined using NMR method.

References

Highly active catalysts for olefin metathesis in water
- K. Skowerski, G. Szczepaniak, C. Wierzbicka, Ł. Gułajski, M. Bieniek, K. Grela, Catal. Sci. Technol. 2012, 2424.

Application

Ring Closing Metathesis in Water Media

References

Highly active catalysts for olefin metathesis in water
- K. Skowerski, G. Szczepaniak, C. Wierzbicka, ?. Gu?ajski, M. Bieniek, K. Grela, Catal. Sci. Technol. 2012, 2424.

Application

Mesoporous Silica Supported Metathesis Catalyst

References

Ru-based complexes with quaternary ammonium tag immobilized on mesoporous silica as olefin metathesis catalysts
- J. Pastva, K. Skowerski, S. J. Czarnocki, N. Zilkova, J. Cejka, Z. Bastl, H. Balcar, ACS Catal. 2014, 4, 3227.

Articles/Brochures

Metathesis Reaction Reagents

Metathesis Catalyst Usable in Water Media: AquaMet

Olefin Polymerization Catalysts

N-Heterocyclic Carbene (NHC) Ligands & Metal Complexes

TCIMAIL

[Product Highlights] Metathesis Catalyst Usable in Water Media
[TCI Practical Example] Olefin Metathesis with AquaMet

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Appearance	Light yellow to Amber to Dark green powder to crystal
Purity(HPLC)	min. 95.0 area%

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CAS RN: 1414707-08-6 | Product Number: A3009

AquaMet

Used Chemicals

Procedure

Experimenter's Comments

Analytical Data（Diethyl cyclopent-3-ene-1,1-dicarboxylate）

Lead Reference

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CAS RN: 1414707-08-6 | Product Number: A3009

AquaMet

Used Chemicals

Procedure

Experimenter's Comments

Analytical Data（Diethyl cyclopent-3-ene-1,1-dicarboxylate）

Lead Reference

References

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Safety Data Sheet (SDS)

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