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CAS RN: 1155843-79-0 | Product Number: H1404
2-Hydroxy-2-azaadamantane
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Purity: >98.0%(T)
Synonyms:
- AZADOL®
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 200MG |
$99.00
|
1 | 1 | 4 |
|
| 1G |
$297.00
|
1 | Contact Us | 17 |
|
| 5G |
$1,083.00
|
6 | 1 | 13 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Supplemental Product Information:
AZADOL® is a registered trademark of Nissan Chemical Industries, Ltd.
| Product Number | H1404 |
| Purity / Analysis Method | >98.0%(T) |
| Molecular Formula / Molecular Weight | C__9H__1__5NO = 153.23 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Packaging and Container | 200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 1155843-79-0 |
| Reaxys Registry Number | 21286916 |
| PubChem Substance ID | 172089100 |
Specifications
| Appearance | White to Gray to Brown powder to crystal |
| Purity(GC) | min. 97.0 % |
| Purity(Nonaqueous Titration) | min. 98.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
Related Laws:
Transport Information:
| HS Number | 2933.99.9701 |
Application
AZADO Catalyzed One-Pot Oxidative Cleavage of Vicinal Diols to (Di)Carboxylic Acids
Typical Procedure (R1 = BzO(CH2)7-, R2 = H): To a solution of 9,10-dihydroxydecyl benzoate (30.0 mg, 0.102 mmol) in CH2Cl2 (0.26 mL) and H2O (0.26 mL) is added AZADOL (1.6 mg, 0.0102 mmol) and PhI(OAc)2 (164 mg, 0.510 mmol) at 0 °C. The mixture is allowed to warm to room temperature and stirred for 1 h. Then, 10% HCl is added to the mixture and the resultant solution is extracted with CH2Cl2. The combined organic layer is washed with brine, dried over MgSO4 and concentrated under reduced pressure. The crude product is purified by silica gel column chromatography (eluent: AcOEt/Hexane = 1/8 to only AcOEt) to give 9-(benzoyloxy)nonanoic acid (26.8 mg, 0.0963 mmol, 94%) as white solid.
References
- 1)M. Shibuya, T. Shibuta, H. Fukuda, Y. Iwabuchi, Org. Lett. 2012, 14, 5010.
- 2)A review on AZADO for oxidation of alcohols.
Application
Alcohol Oxidation Catalyst Showing Higher Activity than TEMPO
References
- 1)Y. Iwabuchi, Chem. Pharm. Bull. 2013, 61, 1197.
- 2)M. Shibuya, Y. Sasano, M. Tomizawa, T. Hamada, M. Kozawa, N. Nagahama, Y. Iwabuchi, Synthesis 2011, 3418.
- 3)Y. Iwabuchi, M. Shibuya, M. Tomizawa, Y. Osada, PCT Int. Appl. WO 2009145323, 2009.
- 4)M. Hayashi, M. Shibuya, Y. Iwabuchi, Org. Lett. 2012, 14, 154.
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] Alcohol Oxidation Catalyst Showing Higher Activity than TEMPO[Research Articles] AZADO Catalyzed One-Pot Oxidative Cleavage of Vicinal Diols to (Di)Carboxylic Acids
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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