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CAS RN: 29892-37-3 | Product Number: C2719
Chloro(dimethylsulfide)gold(I)
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Purity: >97.0%(T)
Synonyms:
- (Dimethylsulfide)gold(I) Chloride
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 200MG |
$103.00
|
2 | 2 | 7 |
|
| 1G |
$311.00
|
7 | 5 | ≥100 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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| Product Number | C2719 |
| Purity / Analysis Method | >97.0%(T) |
| Molecular Formula / Molecular Weight | C__2H__6AuClS = 294.55 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive,Heat Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image), 200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 29892-37-3 |
| Reaxys Registry Number | 16499725 |
| PubChem Substance ID | 253660095 |
| MDL Number | MFCD00192090 |
Specifications
| Appearance | White to Light yellow powder to crystal |
| Purity(Argentometric Titration) | min. 97.0 % |
Properties (reference)
| Melting Point | 160 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 : Take off contaminated clothing and wash before reuse. |
Related Laws:
Transport Information:
| HS Number | 2930.90.9251 |
Application
Preparation of Gold(I)-Phosphine complexes
In a 20 mL screw-top vial is dissolved (SMe)2AuCl (C2719, 1.0 equiv) in CH2Cl2, and the resulting solution is cooled in an ice bath. A solution of the desired phosphine (D4501, 0.5 equiv) in CH2Cl2 is added dropwise, and the resulting solution is allowed to warm to room temperature and stirred for two hours. After TLC indicats complete consumption of the starting material, the reaction solution is concentrated in vacuo to yield the desired gold(I) complexes.
References
Application
Preparation of Gold(I)-NHC complexes
Ag2O (0.5 mmol) is added to a solution of the imidazolium ligand (1.0 mmol) in CH2Cl2. The suspension becomes clear after stirring 3 h at room temperature. Then a solution of Me2SAuCl (C2719, 1.0 mmol) in CH2Cl2 is added dropwise. The reaction mixture is stirred for another 4 h. Then the solution is filtered through Celite and the solvent is partially evaporated. Addition of hexane leads to the precipitation of the methiodides.
References
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Safety Data Sheet (SDS)
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Specifications
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