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CAS RN: 13400-13-0 | Product Number: C2204
Cesium Fluoride
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Purity:
Synonyms:
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 25G |
$55.00
|
10 | 7 | ≥100 |
|
| 100G |
$179.00
|
Contact Us | 4 | ≥100 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | C2204 |
| Molecular Formula / Molecular Weight | CsF = 151.90 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic |
| CAS RN | 13400-13-0 |
| Reaxys Registry Number | 6184400 |
| PubChem Substance ID | 125307414 |
| Merck Index (14) | 2012 |
| MDL Number | MFCD00010960 |
Specifications
| Appearance | White powder to crystal |
| Purity | min. 99.0 % |
Properties (reference)
| Melting Point | 602 °C |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H301 + H311 + H331 : Toxic if swallowed, in contact with skin or if inhaled. H314 : Causes severe skin burns and eye damage. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P270 : Do not eat, drink or smoke when using this product. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P362 : Take off contaminated clothing and wash before reuse. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P405 : Store locked up. |
Related Laws:
| RTECS# | FK9650000 |
Transport Information:
| UN Number (DOT-AIR) | UN2923 |
| Class (DOT-AIR) | 8/6.1 |
| Packing Group (TCI-A) | III |
| HS Number | 2826.19.9000 |
Application
Fluorination
References
- Alkali metal fluorides as efficient fluorinating agents. Enantiocontroued synthesis of 2-fluoroalkyl carboxylates and 1-fluoroalkyl benzenes
- A New Class of SN2 Reactions Catalyzed by Protic Solvents: Facile Fluorination for Isotopic Labeling of Diagnostic Molecules
Application
Triisopropylsilylation of Alcohols using TIPS Reagents
Reference
- Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
- P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.
Application
PMB Protection of Alcohols using Dibutyltin Oxide
Reference
- Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
- P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.
Application
[3+2] Cycloaddition of Arynes with CF3CHN2 for the Synthesis of 3-Trifluoromethyl-1H-indazoles
Typical Procedure:
To a 10 mL sealed tube backfilled with Ar is added 2-(trimethylsilyl)phenyl triflate (59.7 mg, 0.2 mmol), CsF (72.9 mg, 0.48 mmol), TEBAC (136.7 mg, 0.6 mmol) and CF3CHN2 (88 mg, 4 mL, 0.2 M, 4.0 eq.) in THF with vigorous stirring at 25 °C for 24 h. The reaction mixture is poured into saturated brine (15 mL) and extracted with ethyl acetate (15 mL×3). The combined organic layers are dried over MgSO4 and concentrated under reduced pressure. The residue is purified by flash chromatography on silica gel to afford the desired 3-trifluoromethylindazole.
To a 10 mL sealed tube backfilled with Ar is added 2-(trimethylsilyl)phenyl triflate (59.7 mg, 0.2 mmol), CsF (72.9 mg, 0.48 mmol), TEBAC (136.7 mg, 0.6 mmol) and CF3CHN2 (88 mg, 4 mL, 0.2 M, 4.0 eq.) in THF with vigorous stirring at 25 °C for 24 h. The reaction mixture is poured into saturated brine (15 mL) and extracted with ethyl acetate (15 mL×3). The combined organic layers are dried over MgSO4 and concentrated under reduced pressure. The residue is purified by flash chromatography on silica gel to afford the desired 3-trifluoromethylindazole.
References
- [3 + 2] Cycloaddition of arynes with CF3CHN2: Access to 3-trifluoromethyl-1H-indazoles
Application
Generation of the First 3,4-Piperidyne and its Cycloaddition Reactions for the Synthesis of Annulated Piperidines
Reference
Application
Palladium-catalyzed Synthesis of Phenanthrene Derivatives using Benzyne and Acetylenes
Reference
- Palladium catalyzed co-trimerization of benzyne with alkynes. A facile method for the synthesis of phenanthrene derivatives
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] Difluoroacetate Derivative for the Synthesis of Difluoromethylaryls[Product Highlights] Morpholine Derivative Usable for Introduction of a Trifluoromethyl Group
[Research Articles] [3+2] Cycloaddition of Arynes with CF3CHN2 for the Synthesis of 3-Trifluoromethyl-1H-indazoles
[Research Articles] Generation of the First 3,4-Piperidyne and its Cycloaddition Reactions for the Synthesis of Annulated Piperidines
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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