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Published TCIMAIL newest issue No.197
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CAS RN: 17250-25-8 | Product Number: C3040
Carbonylhydridotris(triphenylphosphine)iridium(I)
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Purity:
Synonyms:
- Carbonyltris(triphenylphosphine)iridium(I) Hydride
- Tris(triphenylphosphine)iridium(I) Carbonyl Hydride
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 200MG |
€106.00
|
1 | 7 |
|
| 1G |
€373.00
|
1 | 5 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | C3040 |
| Molecular Formula / Molecular Weight | C__5__5H__4__6IrOP__3 = 1,008.11 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| Packaging and Container | 200MG-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 17250-25-8 |
| Reaxys Registry Number | 17008431 |
| PubChem Substance ID | 253660719 |
| MDL Number | MFCD00015525 |
Specifications
| Appearance | White to Yellow to Green powder to crystal |
| Elemental analysis(Carbon) | 62.00 to 69.00 % |
Properties (reference)
| Melting Point | 170 °C(dec.) |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H301 + H311 + H331 : Toxic if swallowed, in contact with skin or if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P261 : Avoid breathing dust. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. |
Related Laws:
| EC Number | 241-282-7 |
Transport Information:
| UN Number | UN2811 |
| Class | 6.1 |
| Packing Group | III |
| HS Number | 2843909000 |
Application
Addition of Carbonyl Compounds to Triple Bonds of Nitriles via α-C-H Activation
References
- Rhenium-Catalyzed Addition of Carbonyl Compounds to the Carbon-Nitrogen Triple Bonds of Nitriles: α-C-H Activation of Carbonyl Compounds
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