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Published TCIMAIL newest issue No.197
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CAS RN: 7790-86-5 | Product Number: C2058
Cerium(III) Chloride Anhydrous
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Purity: >98.0%(T)
Synonyms:
- Cerous Chloride Anhydrous
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 5G |
€39.00
|
8 | ≥40 |
|
| 25G |
€127.00
|
2 | ≥100 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
| Product Number | C2058 |
| Purity / Analysis Method | >98.0%(T) |
| Molecular Formula / Molecular Weight | CeCl__3 = 246.47 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic |
| CAS RN | 7790-86-5 |
| PubChem Substance ID | 87558579 |
| Merck Index (14) | 1997 |
Specifications
| Appearance | White to Orange to Green powder to crystal |
| Purity(Chelometric Titration) | min. 98.0 % |
Properties (reference)
| Melting Point | 722 °C |
| Solubility in water | Soluble |
| Solubility (soluble in) | Tetrahydrofuran |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
| EC Number | 232-227-8 |
| RTECS# | FK5075000 |
Transport Information:
| HS Number | 2846100090 |
Application
Grignard Reaction
References
- Reactions of carbonyl compounds with Grignard reagents in the presence of cerium chloride
- Use of cerium(III) chloride in the reactions of carbonyl compounds with organolithiums or grignard reagents for the suppression of abnormal reactions:1-butyl-1,2,3,4-tetrahydro-1-naphthol
- Cerium(III) chloride as catalytic and stoichiometric promoter of the quantitative addition of organometallic reagents to (+)-camphor and (-)-fenchone
- Insights into the cerium chloride-catalyzed Grignard addition to esters
PubMed Literature
Product Documents (Note: Some products will not have analytical charts available.)
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