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CAS RN: 16532-02-8 | Product Number: B0847

(Bromomethyl)chlorodimethylsilane


Purity: >95.0%(GC)
Synonyms:
  • Bromomethyldimethylchlorosilane
  • BMDMCS
Product Documents:
5G
$98.00
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25G
$344.00
6   7  

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* The storage conditions are subject to change without notice.


Product Number B0847
Purity / Analysis Method >95.0%(GC)
Molecular Formula / Molecular Weight C__3H__8BrClSi = 187.54 
Physical State (20 deg.C) Liquid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 16532-02-8
Reaxys Registry Number 1071201
PubChem Substance ID 87563828
SDBS (AIST Spectral DB) 10589
MDL Number

MFCD00000503

Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(GC) min. 95.0 %
Properties (reference)
Boiling Point 135 °C
Flash point 41 °C
Specific Gravity (20/20) 1.39
Refractive Index 1.47
GHS
Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H314 : Causes severe skin burns and eye damage.
H226 : Flammable liquid and vapor.
H290 : May be corrosive to metals.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P234 : Keep only in original container.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P390 : Absorb spillage to prevent material damage.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P406 : Store in corrosive resistant container with a resistant inner liner.
P405 : Store locked up.
Related Laws:
Transport Information:
UN Number UN2986
Class 8 / 3
Packing Group II
H.S.code* 2931.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Silylating Reagent for GC-ECD

Experimental procedure:
Hexane (1 mL), diethylamine (0.075 mL) and CMDMCS (0.09 mL) are mixed in a sealable vessel and centrifuged. The resulting supernatant (0.4 mL) is added to sample (100 μg) in ethyl acetate (0.1 mL) and refluxed for 30 min at 65 °C. The mixture is then promptly cooled to room temperature followed by adding hexane to adjust to the appropriate concentration. This solution is injected into GC.

References


PubMed Literature


TCIMAIL
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