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New Carbon Nanoring Material
No.151(August 2013)
Cycloparaphenylenes (CPPs), in which benzene rings are bound to each other at their para positions, represent the shortest sidewall segment (carbon nanoring) of single-walled carbon nanotubes (SWCNTs). In 2009, Itami et al. have reported the first synthesis of [12]cycloparaphenylene (1), which is composed of twelve benzene rings.1a,b) Various applications using 1 are expected.
Moreover, by using 1 as a “template” to grow a nanotube, the selective synthesis of structurally uniform SWCNTs is also expected in the future.2)
References
- 1)Selective Synthesis of [12]Cycloparaphenylene
- 2)The amplification strategy using CPPs for the selective synthesis of SWNTs
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