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CAS RN: 814-29-9 | 產品號碼: T0921

Tributylphosphine Oxide


纯度/分析方法: >95.0%(GC)
別名
  • TBPO
文件:
25G
NT$3,780
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* TCI會時常優化儲存條件,儲存溫度請以在線目錄為準,敬請留意。


產品號碼 T0921
純度/分析方法 >95.0%(GC)
分子式 / 分子量 C__1__2H__2__7OP = 218.32 
外觀與形狀(20°C) Solid
儲存條件 Room Temperature (Recommended in a cool and dark place, <15°C)
儲存在惰性氣體下 Store under inert gas
應避免的情況 Hygroscopic
CAS RN 814-29-9
Reaxys-RN 1761977
PubChem Substance ID 87576741
SDBS (AIST Spectral DB) 15762
MDL編號

MFCD00002082

產品規格
Appearance White to Almost white powder to crystal
Purity(GC) min. 95.0 %
性質
熔點 71 °C
溶解性(可溶於) Methanol
GHS
圖形表示 Pictogram Pictogram
信號詞 Danger
危險性說明 H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled.
H314 : Causes severe skin burns and eye damage.
防範說明 P501 : Dispose of contents/ container to an approved waste disposal plant.
P260 : Do not breathe dusts or mists.
P270 : Do not eat, drink or smoke when using this product.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P405 : Store locked up.
相關法規
RTECS # SZ1575000
運輸資料
UN編號 UN1759
類別 8
包裝類別 III
HS編碼* 2931.49-900
*此H.S.編碼用於日本出口報關, 不適用於您所在國家或地區的進口申報
Application
TCI Practical Example: Regioselective Silylation of an Unprotected Carbohydrate Using the Boronic Acid and the Phosphine Oxide

Regioselective Silylation of an Unprotected Carbohydrate Using the Boronic Acid and the Phosphine Oxide

Used Chemicals

Procedure

To a solution of methyl α-L-fucopyranoside (356 mg, 2 mmol), 4-(dimethylamino)phenylboronic acid (66 mg, 0.4 mmol, 0.2 equiv), tributylphosphine oxide (87 mg, 0.2 mmol, 0.2 equiv) and DIPEA (517 mg, 0.68 mL, 4.0 mmol, 2.0 equiv) in acetonitrile (10 mL) was added TBDPSCl (1.10 g, 1.03 mL, 4.0 mmol, 2.0 equiv) at rt and the mixture was stirred at 60 °C. After 24 h, methanol (1 mL) was added to the reaction mixture and the solvent was removed under reduced pressure. The residue was purified by column chromatography (ethyl acetate:hexane = 0:1 - 1:1 on silica gel) to give 1 as a colorless oil (510 mg,y. 61%).

Experimenter’s Comments

The reaction mixture was monitored by TLC (ethyl acetate:hexane = 1:1, Rf = 0.59).

Analytical Data

Compound 1

1H NMR (400 MHz, CDCl3); δ 7.75-7.67 (m, 4H), 7.48-7.36 (m, 6H), 4.68 (d, 1H, J = 3.2 Hz), 3.93-3.80 (m, 2H), 3.68 (brq, 1H, J = 6.5 Hz), 3.44-3.43 (m, 1H), 3.29 (s, 3H), 2.55 (brs, 1H), 1.53 (d, 1H, J = 8.9 Hz), 1.22 (d, 3H, J = 6.8 Hz), 1.10 (s, 9H).

Lead Reference


考研文獻


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