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CAS RN: 60871-84-3 | 產品號碼: N0861
Nickel(II) Trifluoromethanesulfonate
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| 產品號碼 | N0861 |
| 純度/分析方法 | >96.0%(T) |
| 分子式 / 分子量 | C__2F__6NiO__6S__2 = 356.82 |
| 外觀與形狀（20°C） | Solid |
| 儲存條件 | Room Temperature (Recommended in a cool and dark place, <15°C) |
| 儲存在惰性氣體下 | Store under inert gas |
| 應避免的情況 | Moisture Sensitive |
| 包裝和容器 | 1G-Glass Bottle with Plastic Insert （閲覽圖片） |
| CAS RN | 60871-84-3 |
| Reaxys-RN | 10590495 |
| PubChem Substance ID | 125307294 |
| MDL編號 | MFCD00673740 |
產品規格
| Appearance | Light yellow to Yellow to Green powder to crystal |
| Purity(Chelometric Titration) | min. 96.0 % |
性質
GHS
| 圖形表示 |
|
| 信號詞 | Danger |
| 危險性說明 | H314 : Causes severe skin burns and eye damage. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 : May cause cancer. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P272 : Contaminated work clothing should not be allowed out of the workplace. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
相關法規
運輸資料
| UN編號 | UN1759 |
| 類別 | 8 |
| 包裝類別 | III |
| HS編碼* | 2904.99-000 |
Application
8-アミノキノリン部位を持つ芳香族アミドのC―H結合直接アリール化反応
Typical Procedure (Entry 1):
In an oven-dried 5 mL screw-capped vial in a glovebox, 2-methyl-N-(8-quinolinyl)benzamide (79 mg, 0.3 mmol), iodobenzene (122 mg, 0.6 mmol), Ni(OTf)2 (5 mg, 0.015 mmol), NaHCO3 (50 mg, 0.6 mmol), and toluene (1 mL) are added. The mixture is stirred for 20 h at 160 °C followed by cooling. The mixture is filtered through a Celite pad and concentrated in vacuo. The residue is purified by column chromatography on silica gel (hexane : EtOAc = 10 : 1) to afford the desired arylated product (97 mg, Y. 94%) as a colorless oil.
In an oven-dried 5 mL screw-capped vial in a glovebox, 2-methyl-N-(8-quinolinyl)benzamide (79 mg, 0.3 mmol), iodobenzene (122 mg, 0.6 mmol), Ni(OTf)2 (5 mg, 0.015 mmol), NaHCO3 (50 mg, 0.6 mmol), and toluene (1 mL) are added. The mixture is stirred for 20 h at 160 °C followed by cooling. The mixture is filtered through a Celite pad and concentrated in vacuo. The residue is purified by column chromatography on silica gel (hexane : EtOAc = 10 : 1) to afford the desired arylated product (97 mg, Y. 94%) as a colorless oil.
References
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