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CAS RN: 920-66-1 | 產品號碼: H0424
1,1,1,3,3,3-Hexafluoropropan-2-ol
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產品規格
| Appearance | Colorless to Almost colorless clear liquid |
| Purity(GC) | min. 99.0 % |
| NMR | confirm to structure |
性質
| 熔點 | -4 °C |
| 沸點 | 58 °C |
| 比重 | 1.62 |
| 折射率 | 1.28 |
| Maximum Wavelength | 229 nm |
| 水溶性 | Soluble |
| 溶解性（可溶於） | Ether, Acetone |
GHS
| 圖形表示 |
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| 信號詞 | Danger |
| 危險性說明 | H302 + H332 : Harmful if swallowed or if inhaled. H314 : Causes severe skin burns and eye damage. |
| 防範說明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
相關法規
| RTECS # | UB6450000 |
運輸資料
| UN編號 | UN1760 |
| 類別 | 8 |
| 包裝類別 | III |
| HS編碼* | 2905.59-000 |
Application
1,1,1,3,3,3-Hexafluoro-2-propanol (HFIP or HFP): A Solvent with Specific Properties
1,1,1,3,3,3-Hexafluoro-2-propanol (HFIP or HFP) is used as a solvent with specific properties. Its combination of high H bonding donor ability, low nucleophilicity, and high ionizing power allows reactions to proceed under mild conditions, which usually require the use of added reagents or metal catalysts to be carried out. In addition, HFIP is used as acid in volatile buffers for ion pair HPLC.
References
- Fluorinated alcohols: A new medium for selective and clean reaction (a review)
- 1,1,1,3,3,3-Hexafluoro-2-propanol (a review of the properties, handling and applications)
- 1,1,1,3,3,3-Hexafluoro-2-propanol for the removal of the 4,4'-dimethoxytrityl protecting group from the 5'-hydroxyl of acid-sensitive nucleosides and nucleotides
- New TFA-Free Cleavage and Final Deprotection in Fmoc Solid-Phase Peptide Synthesis: Dilute HCl in Fluoro Alcohol
- Making radical cations live longer
- Analysis of Oligonucleotides by HPLC-Electrospray Ionization Mass Spectrometry
考研文獻
文章/手冊
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![1,1,1,3,3,3-Hexafluoropropan-2-ol [for HPLC]](/medias/H1793.jpg?context=bWFzdGVyfHJvb3R8MTEwNzl8aW1hZ2UvanBlZ3xhREppTDJoak5DODVNek13TXpBd01qSXpOVEU0TDBneE56a3pMbXB3Wnd8NWIxMjU5YWVlMzA1MTMwM2M3ZmZmMWRjNGRlZWRhMDdiMGM5ZDE5ODZmNTJmYTEzYmMwZWUzOGI2NDUyMTYwMA "1,1,1,3,3,3-Hexafluoropropan-2-ol [for HPLC]")