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CAS RN: 12150-46-8 | Product Number: B2027
1,1'-Bis(diphenylphosphino)ferrocene
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Purity: >96.0%(T)
Synonyms:
- 1,1'-Ferrocenebis(diphenylphosphine)
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
NT$1,400
|
14 | 37 | Contact Us | |
| 5G |
NT$4,160
|
19 | 38 | Contact Us | |
| 25G |
NT$17,560
|
22 | 10 | Contact Us |
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| Product Number | B2027 |
| Purity / Analysis Method | >96.0%(T) |
| Molecular Formula / Molecular Weight | C__3__4H__2__8FeP__2 = 554.39 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 12150-46-8 |
| PubChem Substance ID | 87564906 |
| MDL Number | MFCD00001422 |
Specifications
| Appearance | Light yellow to Brown powder to crystaline |
| Purity(Chelometric Titration) | min. 96.0 % |
Properties (reference)
| Melting Point | 182 °C(dec.) |
| Solubility in water | Insoluble |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P261 : Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. |
Related Laws:
Transport Information:
| H.S.code* | 2931.49-900 |
Application
Synthesis of Carbinols
Typical procedure: Under an air atmosphere, a Schlenk tube is charged with Cu(OAc)2·H2O (4.0 mg, 0.02 mmol), dppf (16.6 mg, 0.03 mmol), arylboronic acid (0.4 mmol), aldehyde (0.2 mmol), NaOAc (49.2 mg, 0.6 mmol), and toluene (3 mL) under ice-salt (-20 °C). The mixture is stirred for 0.5 h at room temperature, refluxed for 24 h, and then cooled in a Schlenk tube to room temperature. The mixture is extracted with ethyl acetate (4×5 mL), and the organic layers are washed with water. The organic layers are dried over MgSO4, concentrated, and purified by flash column chromatography on silica gel to give the desired product.
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