用于引入叠氮基和重氮基的磺酰叠氮化物

2,4,6-三异丙基苯磺酰叠氮化物 (1)可以用作亲电叠氮化剂或重氮化剂^1,2)。当1和适当的碱作用于含羰基的底物时，可以在α-位引入叠氮基或重氮基。最近，也有报道使用可见光氧化还原催化剂的脱羧叠氮化反应³⁾。例如，使用脯氨酸衍生物为底物，生成2-叠氮基吡咯烷衍生物。

关键词

T3434

2,4,6-三异丙基苯磺酰叠氮化物 (约10%水润湿品)

T0054

四丁基溴化铵

C0860

18-冠-6-醚

P2844

氢氧化钾 (粉末)

R0039

罗丹明6G

文献

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