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CAS RN: 5707-04-0 | 产品编码: P1091
技术规格
Appearance | Light yellow to Brown powder to crystal |
Purity(Iodometric Titration) | min. 97.0 % |
Melting point | 59.0 to 64.0 °C |
物性(参考值)
熔点 | 63 °C |
沸点 | 95 °C/6 mmHg |
溶解性(可溶于) | 甲醇 |
GHS
象形图 | |
信号词 | Danger |
危险性说明 | H300 + H330 : Fatal if swallowed or if inhaled. H314 : Causes severe skin burns and eye damage. H373 : May cause damage to organs through prolonged or repeated exposure. H410 : Very toxic to aquatic life with long lasting effects. |
防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 : Wear respiratory protection. P391 : Collect spillage. P314 : Get medical advice/ attention if you feel unwell. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P405 : Store locked up. |
相关法规
运输信息
UN编号 | UN2928 |
类别 | 6.1 / 8 |
包装类别 | II |
HS编码* | 2931.90-000 |
应用
Organoselenium Reagent
References
- K. B. Sharpless, R. F. Lauer, A. Y. Teranishi, J. Am. Chem. Soc. 1973, 95, 6137.
- K. C. Nicolaou, Z. Lysenko, Tetrahedron Lett. 1977, 18, 1257.
- T. R. Hoye, A. J. Caruso, J. Org. Chem. 1981, 46, 1198.
- A. Toshimitsu, T. Aoai, H. Owada, S. Uemura, M. Okano, Tetrahedron 1985, 41, 5301.
- A. Toshimitsu, K. Terao, S. Uemura, J. Org. Chem. 1987, 52, 2018.
- K. C. Nicolaou, Tetrahedron 1981, 37, 4097.
- D. L. J. Clive, P. L. Beaulieu, J. Chem. Soc., Chem. Commun. 1983, 307.
参考文献
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