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CAS RN: 92220-65-0 | 产品编码: D5744
Dichlorotetrakis[2-(2-pyridinyl)phenyl]diiridium(III)
技术规格
Appearance | Light orange to Yellow to Green powder to crystal |
Purity(HPLC) | min. 98.0 area% |
NMR | confirm to structure |
物性(参考值)
GHS
象形图 | |
信号词 | Warning |
危险性说明 | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
防范说明 | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
相关法规
运输信息
HS编码* | 2843.90-000 |
应用
Preparing for Iridium-Organic Unit of Photoredox-active MOF
A mixture of H2dcbpy [B3502] (2 mmol, 0.5 g) and Ir2(ppy)4Cl2 [D5744] (1 mmol, 1 g) is dissolved in CH3OH (100 mL). Excessive Na2CO3 is added to the reaction mixture and then heated to reflux under stirring for 5 h. After cooling to room temperature, the solvent is removed under rotary evaporation. Deionized water is added to dissolve the precipitation by stirring, and the complex is achieved by the addition of hydrochloric acid, and then filtered and dried (82% yield based on Ir).
References
- A Dynamic Entangled Framework Based on an Iridium-Organic Unit Showing Reversible Luminescence Turn-on Sensing
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