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CAS RN: 29892-37-3 | 产品编码: C2719
| 产品编码 | C2719 |
| 纯度/分析方法 | >97.0%(T) |
| 分子式/分子量 | C__2H__6AuClS = 294.55 |
| 外观与形状（20°C） | 固体 |
| 储存温度 | 冷藏 (0-10°C) |
| 储存在惰性气体下 | 存放于惰性气体之中 |
| 应避免的情况 | 光,空气,加热 |
| 包装和容器 | 1G-Glass Bottle with Plastic Insert （查看图片）, 200MG-Glass Bottle with Plastic Insert （查看图片） |
| CAS RN | 29892-37-3 |
| Reaxys-RN | 16499725 |
| PubChem物质ID | 253660095 |
| MDL编号 | MFCD00192090 |
技术规格
| Appearance | White to Light yellow powder to crystal |
| Purity(Argentometric Titration) | min. 97.0 % |
物性（参考值）
| 熔点 | 160 °C(dec.) |
GHS
| 象形图 |
|
| 信号词 | Warning |
| 危险性说明 | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| 防范说明 | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
相关法规
运输信息
| HS编码* | 2930.90-900 |
应用
Preparation of Gold(I)-Phosphine complexes
In a 20 mL screw-top vial is dissolved (SMe)2AuCl (C2719, 1.0 equiv) in CH2Cl2, and the resulting solution is cooled in an ice bath. A solution of the desired phosphine (D4501, 0.5 equiv) in CH2Cl2 is added dropwise, and the resulting solution is allowed to warm to room temperature and stirred for two hours. After TLC indicats complete consumption of the starting material, the reaction solution is concentrated in vacuo to yield the desired gold(I) complexes.
References
应用
Preparation of Gold(I)-NHC complexes
Ag2O (0.5 mmol) is added to a solution of the imidazolium ligand (1.0 mmol) in CH2Cl2. The suspension becomes clear after stirring 3 h at room temperature. Then a solution of Me2SAuCl (C2719, 1.0 mmol) in CH2Cl2 is added dropwise. The reaction mixture is stirred for another 4 h. Then the solution is filtered through Celite and the solvent is partially evaporated. Addition of hexane leads to the precipitation of the methiodides.
References
参考文献
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