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CAS RN: 1079-66-9 | 产品编码: C0597

Chlorodiphenylphosphine


纯度/分析方法: >97.0%(T)
别名:
  • 二苯基氯化膦
  • 二苯基氯膦
  • Diphenylphosphinous Chloride
产品文档:
25G
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100G
S$214.50
26   ≥100  请联系我们
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产品编码 C0597
纯度/分析方法 >97.0%(T)
分子式/分子量 C__1__2H__1__0ClP = 220.64 
外观与形状(20°C) 液体
储存温度 室温 (15°C以下阴凉干燥处)
储存在惰性气体下 存放于惰性气体之中
应避免的情况 空气,湿气 (分解)
CAS RN 1079-66-9
Reaxys-RN 512032
PubChem物质ID 87565694
SDBS (AIST Spectral DB) 10853
MDL编号

MFCD00000529

技术规格
Appearance Colorless to Light yellow to Light orange clear liquid
Purity(Argentometric Titration) min. 97.0 %
物性(参考值)
沸点 215 °C/57 mmHg
闪点 138 °C
比重 1.20
折射率 1.64
水溶性 与水接触发生分解, 不溶
GHS
象形图 Pictogram
信号词 Danger
危险性说明 H314 : Causes severe skin burns and eye damage.
防范说明 P501 : Dispose of contents/ container to an approved waste disposal plant.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 : Wash contaminated clothing before reuse.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P405 : Store locked up.
相关法规
运输信息
UN编号 UN3265
类别 8
包装类别 II
HS编码* 2931.59-000
*此H.S.编码用于日本出口报关,不适用于您所在国家或地区的进口申报
应用
A Novel Synthesis of Phenyleneethynylenes by Using Ph2P(O)-protected Ethynes

C0597

Typical Procedure1a):
A toluene (10 mL) solution of 4-ethynylanisole (132 mg, 1.0 mmol), CuI (19 mg, 0.1 mmol), Ph2PCl (265 mg, 1.2 mmol) and Et3N (202 mg, 2.0 mmol) is stirred at 80 °C for 8 h. After workup with CH2Cl2 and NH4Cl(aq), the combined organic layer is washed with brine, and dried over MgSO4. After evaporation, the residue is purified by column chromatography on silica gel (eluent: hexane/CH2Cl2 = 6/1-4/1) to give ((4-methoxyphenyl)ethynyl)diphenylphosphine as pale yellow sticky gel (193 mg, 61%).
To a THF (10 mL) solution of ((4-methoxyphenyl)ethynyl)diphenylphosphine (316 mg, 1.0 mmol) is added H2O2(aq) (30%, 2.5 mL, 20 mmol) at 0 °C, and the mixture is stirred at rt for 2 h. After workup with CH2Cl2 and water, the combined organic layer is washed with brine and dried over MgSO4. After evaporation, the residue is purified by column chromatography on silica gel (eluent: hexane/AcOEt = 2/1) to afford ((4-methoxyphenyl)ethynyl)diphenylphosphine oxide as white powder (312 mg, 94%).
To a THF solution (10 mL) of ((4-methoxyphenyl)ethynyl)diphenylphosphine oxide (166 mg, 0.5 mmol) is added t-BuOK (84 mg, 0.75 mmol), and the mixture is stirred at rt for 2 h. After workup with CH2Cl2 and NH4Cl(aq), the combined organic layer is washed with brine and dried over MgSO4. After evaporation, the residue is purified by column chromatography on silica gel (eluent: hexane) to afford 4-ethynylanisole as pale yellow oil (60 mg, 91%).

References


应用
Mukaiyama Oxidation-Reduction Condensation

[Experimental procedure]
to a mixture of alkoxydiphenylphosphine (2, 0.60 mmol), prepared from the alcohol (1), n-BuLi and chlorodiphenylphosphine, and tetrafluoro-1,4-benzoquinone (0.72 mmol) under argon atmosphere is added a dichloromethane (0.50 mL) solution of alcohol (3, 0.72 mmol) at room temperature. After the reaction that is monitored by TLC was completed, the reaction mixture is quenched by adding water and the aqueous layer is extracted with dichloromethane. The organic layers are dried over anhydrous sodium sulfate. After filtration and evaporation, the resulted residue is purified by preparative TLC to afford the corresponding ether (4).

References


参考文献


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