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CAS RN: 36620-11-8 | 产品编码: B2091
Bis[η-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate
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![Bis[η-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Bis[η-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate")
| 产品编码 | B2091 |
| 分子式/分子量 | C__1__4H__1__6BF__4Rh = 373.99 |
| 外观与形状（20°C） | 固体 |
| 储存温度 | 冷藏 (0-10°C) |
| 储存在惰性气体下 | 存放于惰性气体之中 |
| 应避免的情况 | 空气,湿气 (分解),加热 |
| 包装和容器 | 100MG-Glass Bottle with Plastic Insert （查看图片） |
| CAS RN | 36620-11-8 |
| Reaxys-RN | 14305268 |
| PubChem物质ID | 87564962 |
| MDL编号 | MFCD00671775 |
技术规格
| Appearance | Orange to Brown to Dark red powder to crystal |
| Elemental analysis(Carbon) | 43.00 to 47.00 % |
| NMR | confirm to structure |
物性（参考值）
| 熔点 | 140 °C |
GHS
| 象形图 |
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| 信号词 | Danger |
| 危险性说明 | H302 : Harmful if swallowed. H314 : Causes severe skin burns and eye damage. |
| 防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P270 : Do not eat, drink or smoke when using this product. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
相关法规
运输信息
| UN编号 | UN1759 |
| 类别 | 8 |
| 包装类别 | III |
| HS编码* | 2843.90-000 |
应用
Rhodium Catalyzed Enantioselective Hydroacylation of Acrylamide Derivatives
References
- Rhodium-Catalyzed Highly Enantioselective Direct Intermolecular Hydroacylation of 1,1-Disubstituted Alkenes with Unfunctionalized Aldehydes
- Searching for Practically Useful P-Chirogenic Phosphine Ligands
参考文献
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