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CAS RN: 14548-46-0 | 产品编码: B0306
4-Benzoylpyridine
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技术规格
| Appearance | White to Orange to Green powder to crystal |
| Purity(GC) | min. 98.0 % |
| Purity(Nonaqueous Titration) | min. 99.0 % |
| Melting point | 70.0 to 73.0 °C |
| Solubility in Methanol | almost transparency |
| NMR | confirm to structure |
物性（参考值）
| 熔点 | 72 °C |
| 沸点 | 130 °C/1 mmHg |
| 溶解性（可溶于） | 甲醇 |
GHS
| 象形图 |
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| 信号词 | Warning |
| 危险性说明 | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| 防范说明 | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
相关法规
| RTECS# | OB6402000 |
运输信息
| HS编码* | 2933.39-000 |
应用
Oxidant for Photo-oxidation of Alcohols
Experimental procedure: An acetone solution (5 mL) of cyclododecanol (92.2 mg, 0.5 mmol) and 4-benzoylpyridine (109.9 mg, 0.6 mmol) is placed in a test tube under Ar atmosphere. The test tube is placed at ca. 5 cm distance from a UV-lamp and is irradiated using a 100 W medium-pressure mercury lamp at room temperature for 48 h. After consumption of the alcohol, the solution is evaporated to remove volatile materials. The residue is purified by silica gel column chromatography (hexane:AcOEt = 100:1 - 10:1) to afford cyclododecanone in 78% yield (70.7 mg).
References
- Photoinduced Oxidation of Secondary Alcohols Using 4-Benzoylpyridine as an Oxidant
PubMed Literature