Maximum quantity allowed is 999
请选择数量
CAS RN: 99-33-2 | 产品编码: A5511
3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]
![Thumbnail of 3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]](/medias/A5511.jpg?context=bWFzdGVyfHJvb3R8MTU0MjB8aW1hZ2UvanBlZ3xhR0ZsTDJnMVpDODRPVE16TVRneE5qZzFOemt3TDBFMU5URXhMbXB3Wnd8MTUzOWY5YjQ2YjZkMThlZmRjYmQxZTI0ZWUzZDQ5MjJmNzdjYWU2ODkwNTdmNTMwZDJiOTM3MjU3ZjJiNTg4YQ "3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]")
![Thumbnail of 3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]](/medias/A5511-5G-JP-PM1144-23-Tci-98.webp?context=bWFzdGVyfHByb2R1Y3QtaW1hZ2VzfDg4MnxpbWFnZS93ZWJwfGFHSTRMMmd3WWk4NU5qTTJOall6TURBeE1URTRMMEUxTlRFeExUVkhMVXBRTFZCTk1URTBOQzB5TXkxVVkya3RPVGd1ZDJWaWNBfGI0ZjUxMTQ3YTM5ZGNkMzQzNTI1YjU3ODVlNmFhYjcwMjg2NDczNzg1ZGFhZjAyOTViMTE0NTc5YTkwNTM5MjE "3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]")
![Chemical Structure of 3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]](/medias/A5511.jpg?context=bWFzdGVyfHJvb3R8NTE2NDV8aW1hZ2UvanBlZ3xhR0l3TDJobU1TODRPVEU1TnpNNU5UazJPRE13TDBFMU5URXhMbXB3Wnd8Nzc0N2IzZDBjNTAxODQ5NDEyYjU1NGFhZWI3MTZlNGVmZDYxY2JiMGI4NTRmZmEzYTcyYjEyNjZiZGYyYjNiZA "3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]")
![Chemical Structure of 3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]](/medias/A5511-5G-JP-PM1144-23-Tci-440.webp?context=bWFzdGVyfHByb2R1Y3QtaW1hZ2VzfDgyOTJ8aW1hZ2Uvd2VicHxhRGN6TDJnMU9TODVOak0yTmpZeU9EY3dNRFEyTDBFMU5URXhMVFZITFVwUUxWQk5NVEUwTkMweU15MVVZMmt0TkRRd0xuZGxZbkF8ZTQ1ZjEyYTJhMTJlMTY3ZTk3ZjRlMGEzZDJjNTFkNmViMTQ1OTBmZjU2ZjJlZDZkNDZiYjM0ZTdjY2M4OTdmNA "3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]")
×
![3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]](/_ui/responsive/theme-tci/images/missing_product_zoom.webp "3,5-Dinitrobenzoyl Chloride [for HPLC Labeling]")
| 规格 | 单价 | 同一天 | 2-3个工作日 | 左侧以上货期 | 数量 |
货期信息
|
|---|---|---|---|---|---|---|
| 5G |
S$114.00
|
≥100 | 10 | 下单后约2周内可以发货 |
|
技术规格
| Appearance | White to Orange to Green powder to crystal |
| Purity(Argentometric Titration) | min. 99.0 % |
| Melting point | 68.0 to 71.0 °C |
| Solubility in Toluene | almost transparency |
| Effect test of HPLC derivatization | Effective as labeling agent for 1-Butanol |
| NMR | confirm to structure |
物性（参考值）
| 熔点 | 70 °C |
| 沸点 | 201 °C/17 mmHg |
| 溶解性（可溶于） | 甲苯, 苯 |
GHS
| 象形图 |
|
| 信号词 | Danger |
| 危险性说明 | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. H314 : Causes severe skin burns and eye damage. H341 : Suspected of causing genetic defects. H290 : May be corrosive to metals. |
| 防范说明 | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P234 : Keep only in original container. P201 : Obtain special instructions before use. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P390 : Absorb spillage to prevent material damage. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P406 : Store in corrosive resistant container with a resistant inner liner. P405 : Store locked up. |
相关法规
| RTECS# | DM6637000 |
运输信息
| UN编号 | UN3261 |
| 类别 | 8 |
| 包装类别 | III |
| HS编码* | 2916.39-000 |
应用
HPLC Labeling Reagent for Alcohols and Amines
The compound 1 is an HPLC labeling reagent, which easily reacts with a hydroxyl group or an amino group to form the corresponding ester or amide, respectively. The resultant ester or amide is stable and can reach the detector without any decomposition under reversed phase HPLC. An excellent chromatogram can be obtained by measuring at 254 nm, an absorption wavelength that is generally used for UV detection.
Application examples:
[Alcohols] 1)
Dissolve 1~5 mg of a sample in 5 mL of THF, and add 40 mg of the labeling reagent 1 and a few drops of pyridine. Close the cap of the reaction vessel and incubate the solution at 60 °C for 1 h. Cool the resultant solution to room temperature and use it as an HPLC sample.
Clean up before injection is recommended when pyridine or triethylamine is added to trap generated HCl. Generally, evaporate the solvent, extract with ether and wash the ether layer with diluted hydrochloric acid and water.
[Others]
Analysis of mono- and diethylene glycols in polyethylene glycol2), aliphatic alcohols3)
[Alcohols] 1)
Dissolve 1~5 mg of a sample in 5 mL of THF, and add 40 mg of the labeling reagent 1 and a few drops of pyridine. Close the cap of the reaction vessel and incubate the solution at 60 °C for 1 h. Cool the resultant solution to room temperature and use it as an HPLC sample.
Clean up before injection is recommended when pyridine or triethylamine is added to trap generated HCl. Generally, evaporate the solvent, extract with ether and wash the ether layer with diluted hydrochloric acid and water.
[Others]
Analysis of mono- and diethylene glycols in polyethylene glycol2), aliphatic alcohols3)
TCI Products Pamphlet
HPLC Labeling Reagents ( PDF 10MB )
HPLC Labeling Reagents ( PDF 10MB )
References
- 1)T. H. Jupille, Am. Lab. 1976, 8, 85.
- 2)M. A. Carey, H. E. Persinger, J. Chromatogr. Sci. 1972, 10, 537.
- 3)Y. Suzuki, N. Tsuchiya, Bunseki Kagaku 1981, 30, 240.
- 4)L. J. Elrod, L. B. White, S. G. Spanton, D. G. Stroz, P. J. Cugier, L. A. Luka, Anal. Chem. 1984, 56, 1786.
PubMed Literature
技术文章
产品文档 (部分产品的分析图谱无法提供，敬请谅解。)
化学品安全说明书(SDS)
请选择语言。
如需更多帮助，请联系我 们。
技术规格
CoA及其他文档
请输入批号
批号输入有误。请输入中横线前的4-5个字母数字字符。
示例 CoA
可下载CoA示例。注：该示例不一定是最新批次的CoA。
目前没有该产品的 CoA 示例。
分析图谱
请输入批号
批号输入有误。请输入中横线前的4-5个字母数字字符。
很抱歉，您搜索的分析图谱无法提供。
