Published TCIMAIL newest issue No.197
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CAS RN: | Product Number: Z0035
ZnTAC24® (contains 7% Toluene at maximum)
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Purity:
Synonyms:
- Oxo[hexa(trifluoroacetato)]tetrazinc and its trifluoroacetic acid adduct (contains 7% Toluene at maximum)
Product Documents:
| Size | Unit Price | Belgium | Japan* | Quantity |
|---|---|---|---|---|
| 1G |
€18.00
|
3 | ≥40 |
|
| 5G |
€79.00
|
1 | ≥100 |
|
*Stock available in Belgium will be delivered in 1 to 3 days
*Stock available in Japan will be delivered in 1 to 2 weeks (excludes regulated items and dry ice shipments).
Supplemental Product Information:
This product cannot be shipped to Russia and Turkey.
This product was merchandised under the technical tie-up with TAKASAGO INTERNATIONAL CORPORATION. ZnTAC24® is a registered trademark of TAKASAGO INTERNATIONAL CORPORATION.
We offer this product only in quantities for laboratory use.
| Product Number | Z0035 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| Related CAS RN | 906672-87-5&1299489-47-6 |
| PubChem Substance ID | 354335824 |
Specifications
| Appearance | White to Light gray to Light yellow powder to crystal |
| Zinc | 24 to 28 % |
Properties (reference)
| Solubility in water | Insoluble |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H360 : May damage fertility or the unborn child. H371 : May cause damage to organs. H373 : May cause damage to organs through prolonged or repeated exposure. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust. P202 : Do not handle until all safety precautions have been read and understood. P201 : Obtain special instructions before use. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing protection. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. |
Related Laws:
Transport Information:
| HS Number | 2931900090 |
Application
Acetylation of Alcohols via Transesterification using Acetylating Reagents
References
- 1)A Simple, General, and Highly Chemoselective Acetylation of Alcohols Using Ethyl Acetate as the Acetyl Donor Catalyzed by a Tetranuclear Zinc Cluster
- 2)Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
- P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.
Application
Carbon-dioxide C=O Bond Activation/cycloaddition
Reference
- Efficient Cyclic Carbonate Synthesis Catalyzed by Zinc Cluster Systems under Mild Conditions
Application
Ester Oxazolination
Reference
- Direct Conversion of Esters, Lactones, and Carboxylic Acids to Oxazolines Catalyzed by a Tetranuclear Zinc Cluster
Application
Acetyl Selective Ester Hydrolysis
Reference
- A Tetranuclear-Zinc-Cluster-Catalyzed Practical and Versatile Deprotection of Acetates and Benzoates
Application
Chemoselective Acylation of Aminoalcohols
Reference
- Enzyme-Like Chemoselective Acylation of Alcohols in the Presence of Amines Catalyzed by a Tetranuclear Zinc Clusterl
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