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CAS RN: 811-68-7 | Product Number: S0977
Silver(I) Trifluoromethanethiolate
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Purity: >95.0%(T)
Synonyms:
- Trifluoromethanethiol Silver(I) Salt
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
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|---|---|---|---|---|---|
| 1G |
$124.00
|
2 | ≥60 | Contact Us | |
| 5G |
$434.00
|
12 | ≥60 | Contact Us |
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| Product Number | S0977 |
| Purity / Analysis Method | >95.0%(T) |
| Molecular Formula / Molecular Weight | CAgF__3S = 208.93 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 811-68-7 |
| Reaxys Registry Number | 4151922 |
| PubChem Substance ID | 354333285 |
| MDL Number | MFCD25563234 |
Specifications
| Appearance | White to Light yellow to Light red powder to crystal |
| Purity(Precipitation Titration) | min. 95.0 % |
Properties (reference)
| Solubility in water | Insoluble |
| Solubility (slightly sol. in) | Methanol |
GHS
Related Laws:
Transport Information:
| H.S.code* | 2843.29-000 |
Application
Trifluoromethylthiolating Agent Usable for Direct Dehydroxytrifluoromethylthiolation of Alcohols
Experimental procedure3): AgSCF3 (251 mg, 1.2 mmol, 3.0 eq.) and TBAI (1330 mg, 3.6 mmol, 9.0 eq.) are combined in a Schlenk tube. The tube is mounted with a reflux condenser and backfilled with N2, then toluene (4.0 mL) and alcohol (0.4 mmol, 1.0 eq.) are added. The tube is placed into a preheated oil bath at 80 °C with vigorous stirring. After 10 h, the reaction mixture is cooled to room temperature and filtered through a plug of silica (eluted with EtOAc). The filtrate is concentrated, and the product is purified by column chromatography on silica gel to give the desired product.
References
- 1)Pd-Catalyzed Synthesis of Ar-SCF3 Compounds under Mild Conditions
- 2)Silver-Mediated Radical Aryltrifluoromethylthiolation of Activated Alkenes
- 3)Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide
- 4)Preparation of Trifluoromethyl Aryl Sulfides Using Silver(I)Trifluoromethanethiolate and an Inorganic Iodide
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