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CAS RN: 5470-11-1 | Product Number: H1581

Hydroxylamine Hydrochloride


Purity: >97.0%(T)
Synonyms:
  • Hydroxylammonium Chloride
Product Documents:
25G
$18.00
18   ≥100 
500G
$38.00
9   ≥100 

* Please contact our distributors or TCI to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.


Product Number H1581
Purity / Analysis Method >97.0%(T)
Molecular Formula / Molecular Weight H__3NO·HCl = 69.49 
Physical State (20 deg.C) Solid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Air Sensitive,Hygroscopic
CAS RN 5470-11-1
Reaxys Registry Number 3539763
PubChem Substance ID 354333550
Merck Index (14) 4828
MDL Number

MFCD00051089

Specifications
Appearance White to Almost white powder to crystal
Purity(Redox method) min. 97.0 %
Properties (reference)
Melting Point 151 °C(dec.)
Solubility (soluble in) Alcohol
Solubility (insoluble in) Ether
GHS
Pictogram Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H301 : Toxic if swallowed.
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H319 : Causes serious eye irritation.
H371 : May cause damage to organs.
H373 : May cause damage to organs through prolonged or repeated exposure.
H317 : May cause an allergic skin reaction.
H351 : Suspected of causing cancer.
H335 : May cause respiratory irritation.
H400 : Very toxic to aquatic life.
H290 : May be corrosive to metals.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P273 : Avoid release to the environment.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P202 : Do not handle until all safety precautions have been read and understood.
P234 : Keep only in original container.
P201 : Obtain special instructions before use.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P390 : Absorb spillage to prevent material damage.
P391 : Collect spillage.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention.
P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth.
P302 + P352 + P312 : IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/doctor if you feel unwell.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P406 : Store in corrosive resistant container with a resistant inner liner.
P405 : Store locked up.
Related Laws:
RTECS# NC3675000
Transport Information:
UN Number UN2923
Class 8 / 6.1
Packing Group III
H.S.code* 2825.10-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
TCI Practical Example: Isoxazole Ring Construction Reaction Using Hydroxylamine Hydrochloride

TCI Practical Example: Isoxazole Ring Construction Reaction Using Hydroxylamine Hydrochloride

Used Chemicals

Procedure

Hydroxyamine hydrochloride (396 mg, 6.0 mmol, 1.2 eq.) was added to a solution of 1,3-diphenyl-1,3-propanedione (1.12 g, 5.0 mmol) in EtOH (20 mL) at room temperature and the mixture was refluxed for overnight. Then water (80 mL) was added to the reaction mixture and precipitate was filtered to give 3,5-diphenylisoxazole as a pale red solid (1.09 g, 99% yield).

Experimenter’s Comments

The reaction mixture was monitored by UPLC.

Analytical Data

3,5-Diphenylisoxazole

1H NMR (400 MHz, CDCl3); δ 7.87-7.83 (m, 4H), 7.50-7.46 (m, 6H), 6.82 (s, 1H).

Lead Reference


PubMed Literature


Articles/Brochures

Product Documents (Note: Some products will not have analytical charts available.)
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