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CAS RN: 543-75-9 | Product Number: D2287
1,4-Dioxene
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Purity: >98.0%(GC)
Synonyms:
- 2,3-Dihydro-1,4-dioxine
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
$130.00
|
1 | 11 | It can be shipped in about 5-6 months after ordering | |
| 5G |
$335.00
|
0 | 3 | It can be shipped in about 5-6 months after ordering | |
| 25G |
$1,059.00
|
0 | 0 | It can be shipped in about 5-6 months after ordering |
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to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.
| Product Number | D2287 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__4H__6O__2 = 86.09 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 543-75-9 |
| Reaxys Registry Number | 1310 |
| PubChem Substance ID | 87568724 |
| SDBS (AIST Spectral DB) | 35998 |
| MDL Number | MFCD00082537 |
Specifications
| Appearance | Colorless to Light yellow to Light orange clear liquid |
| Purity(GC) | min. 98.0 % |
Properties (reference)
| Boiling Point | 94 °C |
| Flash point | 1 °C |
| Specific Gravity (20/20) | 1.08 |
| Refractive Index | 1.44 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H225 : Highly flammable liquid and vapor. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P403 + P235 : Store in a well-ventilated place. Keep cool. |
Related Laws:
Transport Information:
| UN Number | UN1993 |
| Class | 3 |
| Packing Group | II |
| H.S.code* | 2932.99-000 |
Application
Useful Synthon
References
- Review : The chemistry of 1,4-Dioxene
- Synthesis of α-keto thioketals
- Synthesis of α,α'-dihydroxy ketones
- Synthesis of α-hydroxymethyl ketones
- Synthesis of α-keto acids
- Photocycloaddition reaction
- a) G. Kaupp, M. Stark, H. Fritz, Chem. Ber. 1978, 111, 3624.
- b) R. Huisgen, L. A. Feiler, P. Otto, ibid. 1969, 102, 3405.
- idem., ibid. 1969, 102, 3444.
- c) N. R. Lazear, J. H. Schauble, J. Org. Chem. 1974, 39, 2069.
- . C. Freilich, K. S. Peters, J. Am. Chem. Soc. 1985, 107, 3819.
- d) J.-M. Bernassau, A. Bouillot, M. Fétizon, I. Hanna, E. R. Maia, J. Org. Chem. 1987, 52, 1993.
- . H. M. Hill, S. T. Reid, J. Chem. Soc., Chem. Commun. 1983, 501.
- . Wenkert, R. S. Greenberg, M. S. Raju, J. Org. Chem. 1985, 50, 4681.
- a) G. Kaupp, M. Stark, H. Fritz, Chem. Ber. 1978, 111, 3624.
PubMed Literature
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Specifications
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