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Manganese Complex for Hydrogen Transfer Reactions

The manganese-PNP complex (1) is a powerful catalyst for hydrogen transfer reactions and is utilized in carbon-nitrogen and carbon-carbon bond formation reactions as well as reductions. 1 catalyzes the reduction of aldehydes, ketones and nitriles with hydrogen gas or alcohols to afford the desired alcohols and amines, respectively.1) 1 can also catalyze the N-alkylation of primary amines with alcohols to convert them into secondary amines.2) Furthermore, 2-arylalcohols are dimerized in the presence of 1 via oxidation of the alcohol, aldol reaction and deformylation.3) In addition to these reactions, the decomposition reaction of aqueous methanol into hydrogen gas and carbon dioxide has been reported.4) In this way, 1 is anticipated as an excellent hydrogen transfer catalyst, and more new reactions using 1 will be developed in the future.

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Manganese-PNP Complex

References

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