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CAS RN: 14437-03-7 | Product Number: M2988
Methyl Tosylcarbamate
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Purity: >98.0%(T)(HPLC)
Synonyms:
- N-(p-Toluenesulfonyl)carbamic Acid Methyl Ester
- Methyl N-(p-Toluenesulfonyl)carbamate
- N-(p-Tosyl)carbamic Acid Methyl Ester
- Methyl N-(p-Tosyl)carbamate
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days |
|---|---|---|---|
| 1G |
$79.00
|
4 | Contact Us |
| 10G |
$628.00
|
16 | Contact Us |
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to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.
| Product Number | M2988 |
| Purity / Analysis Method | >98.0%(T)(HPLC) |
| Molecular Formula / Molecular Weight | C__9H__1__1NO__4S = 229.25 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 14437-03-7 |
| Reaxys Registry Number | 2215519 |
| PubChem Substance ID | 468592243 |
| MDL Number | MFCD00453717 |
Specifications
| Appearance | White to Light yellow powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| Purity(Neutralization titration) | min. 98.0 % |
| Melting point | 108.0 to 112.0 °C |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 110 °C |
GHS
Related Laws:
Transport Information:
| H.S.code* | 2935.90-000 |
Application
TCI Practical Example: Intermolecular Allylic C-H Amination Using White Catalyst
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Used Chemicals
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Procedure
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A test tube with thread under air was charged with 1-decene (0.5 g, 3.56 mmol), MTBE (5.4 mL), White catalyst (181 mg, 0.36 mmol), 1,4-benzoquinone (770 mg, 7.12 mmol),methyl N-(p-toluenesulfonyl)carbamate (1.63 g, 7.12 mmol), N,N-diisopropylethylamine (40 μL, 0.21 mmol) and a magnetic stir bar were then sequentially added. The test tube was fitted with a glass stopper, stirred at 45 °C. After 72 h, the reaction mixture was allowed to cool to room temperature. The suspension was filtrated and washed with diethyl ether (30 mL). The filtrate was washed with 5% sodium carbonate aqueous solution (50 mL), and the aqueous phase was extracted with diethyl ether (30 mL). The combined organic phase was dried over sodium sulfate and filtered. The solvent was removed under reduced pressure and the residue was purified by medium pressure preparative chromatography (silica gel, hexane : ethyl acetate = 5 : 95 - 20 : 80), giving 1 as a yellow oil (0.73 g, 56%).
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Experimenter’s Comments
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The reaction mixture was monitored by TLC (ethyl acetate : hexane = 1 : 3, Rf = 0.58).
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Analytical Data（Compound 1）
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1H NMR (400 MHz, CDCl3); δ 7.81 (d, J = 9.2 Hz, 2H), 7.29 (d, J = 7.8 Hz, 2H), 5.78 (m,1H), 5.51 (m, 1H), 4.40 (d, J = 6.4 Hz, 2H), 3.68 (s, 3H), 2.43 (s, 3H), 2.04 (m, 2H), 1.37 (m, 10H), 0.88 (t, J = 6.7 Hz, 3H).
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Lead References
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- Catalytic Intermolecular Linear Allylic C−H Amination via Heterobimetallic Catalysis
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- A Catalytic, Brønsted Base Strategy for Intermolecular Allylic C−H Amination
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Other References
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- syn-1,2-Amino Alcohols via Diastereoselective Allylic C−H Amination
- Serial Ligand Catalysis: A Highly Selective Allylic C−H Oxidation
Product Documents (Note: Some products will not have analytical charts available.)
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Specifications
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