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CAS RN: 1229444-44-3 | Product Number: M2103
1-Methyl-1-[4-(diphenylphosphino)benzyl]pyrrolidinium Bromide
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![1-Methyl-1-[4-(diphenylphosphino)benzyl]pyrrolidinium Bromide](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "1-Methyl-1-[4-(diphenylphosphino)benzyl]pyrrolidinium Bromide")
Purity: >97.0%(HPLC)
Synonyms:
Product Documents:
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| Product Number | M2103 |
| Purity / Analysis Method | >97.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__2__4H__2__7BrNP = 440.36 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 1229444-44-3 |
| Reaxys Registry Number | 20305096 |
| PubChem Substance ID | 125307290 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(HPLC) | min. 97.0 area% |
| Purity(Iodometric Titration) | min. 97.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
Related Laws:
Transport Information:
| H.S.code* | 2933.99-000 |
Application
Aza-Morita-Baylis-Hillman Reaction with Ion-Supported Ph3P
Typical procedure (Entry 3, R = 4-Fluorophenyl): Methyl vinyl ketone (105 mg) is added to a solution of N-(4’-fluorobenzylidene)-4-methylbenzenesulfonamide (277 mg), 1-methyl-1-[4-(diphenylphosphino)benzyl]pyrrolidinium bromide (220 mg) and MS4Å (100 mg) in CH2Cl2 (4 mL). The mixture is stirred for 5 h at room temperature under an argon atmosphere. After the reaction, diethyl ether (10 mL) is added and the mixture is stirred for 30 min at 0 °C. The mixture is filtered and washed with diethyl ether. Removal of the solvent from the filtrates gives the corresponding product with 95 % purity. The product is purified by short flash column chromatography on silica gel (eluent: AcOEt/hexane=1/2) to give the desired pure product (347 mg, 100 %).
References
Application
Ion-supported Triphenylphosphines
Typical procedure (Entry 3, R = 4-Fluorophenyl): Methyl vinyl ketone (105 mg) is added to a solution of N-(4’-fluorobenzylidene)-4-methylbenzenesulfonamide (277 mg), 1-methyl-1-[4-(diphenylphosphino)benzyl]pyrrolidinium bromide (220 mg) and MS4Å (100 mg) in CH2Cl2 (4 mL). The mixture is stirred for 5 h at room temperature under an argon atmosphere. After the reaction, diethyl ether (10 mL) is added and the mixture is stirred for 30 min at 0 °C. The mixture is filtered and washed with diethyl ether. Removal of the solvent from the filtrates gives the corresponding product with 95 % purity. The product is purified by short flash column chromatography on silica gel (eluent: AcOEt/hexane=1/2) to give the desired pure product (347 mg, 100 %).
References
Application
Wittig Reaction with Ion-supportedPh3
Reference
PubMed Literature
Articles/Brochures
TCIMAIL
[TCIMAIL No.149] Ion-supported Triphenylphosphine[Research Articles] Aza-Morita-Baylis-Hillman Reaction with Ion-Supported Ph3P
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