Maintenance Notice (10:30 PM January 4 - 8:00 AM January 5, 2025 UTC): This website is scheduled to be unavailable due to maintenance. We appreciate your patience and understanding.
Published TCIMAIL newest issue No.197 | Notice of Discontinuing the Use of Password-Protected Compressed Files | Various analytical charts can be searched on each product detail page and Product Document Search (The kinds of analytical charts differ by product)
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 87413-09-0 | Product Number: D2045
Dess-Martin Periodinane
×
![]()
×
Purity: >95.0%(T)
Synonyms:
- 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one
- DMP
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
$59.00
|
4 | 0 | Contact Us | |
| 5G |
$175.00
|
15 | 15 | Contact Us | |
| 25G |
$562.00
|
13 | 0 | Contact Us |
* Please contact our distributors or
TCI
to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.
Supplemental Product Information:
This product may generate a little insoluble matter overtime while storing.
Since no effect the reaction, please filtering as needed before use.
| Product Number | D2045 |
| Purity / Analysis Method | >95.0%(T) |
| Molecular Formula / Molecular Weight | C__1__3H__1__3IO__8 = 424.14 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Frozen (-20°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Light Sensitive,Air Sensitive,Moisture Sensitive,Heat Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 87413-09-0 |
| Reaxys Registry Number | 4548207 |
| PubChem Substance ID | 87568496 |
| Merck Index (14) | 2933 |
| MDL Number | MFCD00130127 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(Iodometric Titration) | min. 95.0 % |
| NMR | confirm to structure |
Properties (reference)
| Melting Point | 124 °C(dec.) |
| Solubility (soluble in) | Chloroform, Acetone |
| Solubility (slightly sol. in) | Ether |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H341 : Suspected of causing genetic defects. H272 : May intensify fire; oxidizer. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P202 : Do not handle until all safety precautions have been read and understood. P220 : Keep/Store away from clothing/ combustible materials. P210 : Keep away from heat. P201 : Obtain special instructions before use. P221 : Take any precaution to avoid mixing with combustibles. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number | UN1479 |
| Class | 5.1 |
| Packing Group | III |
| H.S.code* | 2934.99-000 |
Application
TCI Practical Example: Mild Oxidation Using Dess-Martin Periodinane
Used Chemicals
Procedure
To dichloromethane (10 mL) was added trans-2-phenyl-1-cyclohexanol (0.30 g，1.7 mmol) and DMP (0.72 g, 1.7 mmol) at room temperature. The reaction mixture was stirred overnight at room temperature, then diluted with diethyl ether and washed with saturated aqueous sodium bicarbonate, 10% aqueous sodium thiosulfate, water and brine. The organic layer was concentrated under reduced pressure. The resulting crude product was purified by column chromatography (hexane:ethyl acetate = 8:1 on silica gel) to give 1 as a white solid (0.22 g, 74% yield).
Experimenter’s Comments
The reaction mixtures were monitored by TLC (hexane:ethyl acetate = 4:1).
Analytical Data（2-Phenylcyclohexanone (1)）
1H NMR (400 MHz, CDCl3); δ 7.37-7.31 (m, 2H), 7.30-7.22 (m, 1H), 7.17-7.12 (m, 2H), 3.62 (dd, 1H, J = 12.4, 6.9 Hz), 2.58-2.41 (m, 2H), 2.33-2.23 (m, 1H), 2.22-2.10 (m, 1H), 2.10-1.94 (m, 2H), 1.91-1.75 (m, 2H).
13C NMR (101 MHz, CDCl3); δ 210.5, 138.9, 128.6, 128.5, 127.0, 57.5, 42.3, 35.2, 27.9, 25.5.
Lead Reference
- Acceleration of the Dess-Martin Oxidation by Water
Application
Dess-Martin Periodinane Reagent
References
- M. Horikawa, K. Hashimoto, H. Shirahama, Tetrahedron Lett. 1993, 34, 331.
- J. N. Haseltine, M. P. Cabal, N. B. Mantlo, N. Iwasawa, D. S. Yamashita, R. S. Coleman, S. J. Danishefsky, G. K. Schulte, J. Am. Chem. Soc. 1991, 113, 3850.
- J. P. Burkhart, N. P. Peet, P. Bey, Tetrahedron Lett. 1988, 29, 3433.
- D. B. Dess, J. C. Martin, J. Org. Chem. 1983, 48, 4155.
- R. J. Linderman, D. M. Graves, Tetrahedron Lett. 1987, 28, 4259.
PubMed Literature
Articles/Brochures
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.
Other Documents
Related Products
Dess-Martin Periodinane (8-12% in Dichloromethane)
| Product # | D4477 |
| CAS RN | 87413-09-0 |
| Purity / Analysis Method: |