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CAS RN: 18303-04-3 | Product Number: B1648
N-(tert-Butoxycarbonyl)-p-toluenesulfonamide
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Purity: >98.0%(T)(HPLC)
Synonyms:
- N-Boc-p-toluenesulfonamide
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
Shipping Information
|
|---|---|---|---|---|---|
| 10G |
$77.00
|
≥40 | 9 | Contact Us | |
| 25G |
$141.00
|
37 | 0 | Contact Us |
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| Product Number | B1648 |
| Purity / Analysis Method | >98.0%(T)(HPLC) |
| Molecular Formula / Molecular Weight | C__1__2H__1__7NO__4S = 271.33 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 18303-04-3 |
| Reaxys Registry Number | 2858665 |
| PubChem Substance ID | 87564549 |
| MDL Number | MFCD00134267 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| Purity(Neutralization titration) | min. 98.0 % |
Properties (reference)
| Melting Point | 123 °C |
GHS
Related Laws:
Transport Information:
| H.S.code* | 2935.90-000 |
Application
Sulfonamide Effective for the Introduction of Amino group
Experimental procedure: To a solution of PPh3 (6.23 g, 23.8 mmol) in THF (56 mL) under an atmosphere of nitrogen at 0 °C is added DIAD (3.85 g, 23.8 mmol). The reaction is stirred at 0 °C for 30 min before N-(tert-butoxycarbonyl)-p-toluenesulfonamide (5.37 g, 20.0 mmol) is added. The mixture is allowed to stir at 0 °C for 5 min followed by the addition of 1 (3.11 g, 19.8 mmol). The reaction is stirred at room temperature for 2.5 h before being concentrated under reduced pressure to give a crude oil. The oil is purified by flash column chromatography (silica gel, ethyl acetate:hexanes = 1:20) to generate 2 (7.54 g, 18.4 mmol, 93%) as orange oil.
References
- Iron(II) Halide Promoted Cyclization of Cyclic 2-Enynamides: Stereoselective Synthesis of Halogenated Bicyclic γ-Lactams
Application
Sulfonamide under Mitsunobu Reaction
References
- An efficient route to protected amines
PubMed Literature
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