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CAS RN: 77-78-1 | Product Number: D0797

Dimethyl Sulfate


Purity: >98.0%(GC)
Synonyms:
Product Documents:
25G
$19.00
19   ≥100 
500G
$40.00
35   ≥100 

* Please contact our distributors or TCI to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.


Product Number D0797
Purity / Analysis Method >98.0%(GC)
Molecular Formula / Molecular Weight C__2H__6O__4S = 126.13 
Physical State (20 deg.C) Liquid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Store Under Inert Gas Store under inert gas
Condition to Avoid Moisture Sensitive
CAS RN 77-78-1
Reaxys Registry Number 635994
PubChem Substance ID 125309028
SDBS (AIST Spectral DB) 2891
Merck Index (14) 3256
MDL Number

MFCD00008416

Specifications
Appearance Colorless to Almost colorless clear liquid
Purity(GC) min. 98.0 %
Properties (reference)
Boiling Point 76 °C/15 mmHg
Flash point 123 °C
Specific Gravity (20/20) 1.33
Refractive Index 1.39
Solubility (soluble in) Dioxane, Acetone, Ethanol, Ether
Solubility (slightly sol. in) Aliphatic hydrocarbons
GHS
Pictogram Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H330 : Fatal if inhaled.
H301 : Toxic if swallowed.
H314 : Causes severe skin burns and eye damage.
H361 : Suspected of damaging fertility or the unborn child.
H370 : Causes damage to organs.
H373 : May cause damage to organs through prolonged or repeated exposure.
H317 : May cause an allergic skin reaction.
H341 : Suspected of causing genetic defects.
H350 : May cause cancer.
H335 : May cause respiratory irritation.
H411 : Toxic to aquatic life with long lasting effects.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P273 : Avoid release to the environment.
P272 : Contaminated work clothing should not be allowed out of the workplace.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P270 : Do not eat, drink or smoke when using this product.
P202 : Do not handle until all safety precautions have been read and understood.
P201 : Obtain special instructions before use.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P284 : Wear respiratory protection.
P391 : Collect spillage.
P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor.
P362 + P364 : Take off contaminated clothing and wash it before reuse.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention.
P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth.
P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor.
P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P405 : Store locked up.
Related Laws:
RTECS# WS8225000
Transport Information:
UN Number UN1595
Class 6.1 / 8
Packing Group I
Air Transportation Forbidden for Air Transport
H.S.code* 2920.90-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Methylation of Alcohols using Dimethyl Sulfate

References

  • Protection for the Hydroxyl Group, Including 1,2- and 1,3-Diols
    • P. G. M. Wuts, in Greene’s Protective Groups in Organic Synthesis, 5th ed., ed. by P. G. M. Wuts, John Wiley & Sons, Inc., Hoboken, New Jersey, 2014, Chap. 2, 17.


PubMed Literature


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