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CAS RN: 108-05-4 | Product Number: A0045

Vinyl Acetate Monomer (stabilized with HQ)


Purity: >99.0%(GC)
Synonyms:
  • Acetic Acid Vinyl Ester Monomer (stabilized with HQ)
Product Documents:
500ML
$21.00
≥100  33  

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* The storage conditions are subject to change without notice.


Product Number A0045
Purity / Analysis Method >99.0%(GC)
Molecular Formula / Molecular Weight C__4H__6O__2 = 86.09 
Physical State (20 deg.C) Liquid
Storage Temperature Room Temperature (Recommended in a cool and dark place, <15°C)
Condition to Avoid Light Sensitive,Air Sensitive
CAS RN 108-05-4
Reaxys Registry Number 1209327
PubChem Substance ID 87561748
SDBS (AIST Spectral DB) 1299
Merck Index (14) 9992
MDL Number

MFCD00008713

Specifications
Appearance Colorless clear liquid
Purity(GC) min. 99.0 %
NMR confirm to structure
Properties (reference)
Melting Point -93 °C
Boiling Point 72 °C
Flash point -8 °C
Specific Gravity (20/20) 0.93
Refractive Index 1.40
Solubility in water Slightly soluble
Degree of solubility in water 25 g/l   20 °C
Solubility (miscible with) Ether, Alcohol
Solubility (soluble in) Acetone, Chloroform
GHS
Pictogram Pictogram Pictogram Pictogram
Signal Word Danger
Hazard Statements H332 : Harmful if inhaled.
H320 : Causes eye irritation.
H373 : May cause damage to organs through prolonged or repeated exposure.
H341 : Suspected of causing genetic defects.
H351 : Suspected of causing cancer.
H335 : May cause respiratory irritation.
H401 : Toxic to aquatic life.
H225 : Highly flammable liquid and vapor.
Precautionary Statements P501 : Dispose of contents/ container to an approved waste disposal plant.
P273 : Avoid release to the environment.
P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
P202 : Do not handle until all safety precautions have been read and understood.
P240 : Ground/bond container and receiving equipment.
P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233 : Keep container tightly closed.
P201 : Obtain special instructions before use.
P243 : Take precautionary measures against static discharge.
P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment.
P242 : Use only non-sparking tools.
P271 : Use only outdoors or in a well-ventilated area.
P264 : Wash skin thoroughly after handling.
P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection.
P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
P308 + P313 : IF exposed or concerned: Get medical advice/ attention.
P337 + P313 : If eye irritation persists: Get medical advice/ attention.
P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P403 + P235 : Store in a well-ventilated place. Keep cool.
P405 : Store locked up.
Related Laws:
RTECS# AK0875000
Transport Information:
UN Number UN1301
Class 3
Packing Group II
H.S.code* 2915.32-000
*This code is applied to the products when TCI exports from Japan and not for import in your country.
Application
Acetylation of Alcohols via Biotransformation using Acetylating Reagents

References


Application
Acetylation of Alcohols via Transesterification using Acetylating Reagents

A0045

References


Application
Acetylation of Alcohols using Acetylating Reagents and Acid Catalysts

References


Application
Rhodium-Catalyzed Cross-coupling of Organoboron Compounds with Vinyl Acetate

Typical procedure: Under nitrogen atmosphere, a mixture of an arylboron compounds (0.50 mmol), [RhCl(cod)]2 (6.2 mg, 13 µmol), DPPB (11.7 mg, 28 µmol), and K3PO4 (320 mg, 1.5 mmol) is diluted with toluene (2.0 mL). Alkenyl acetate (1.1 or 2.5 mmol) and tert-amyl alcohol (0.55-1.5 mmol) are added into the resulting suspension at room temperature. The mixture is stirred at 100℃ for 24 h and then diluted with hexane (2.0 mL) or EtOAc (2.0 mL). After the filtration through a Celite pad, solvent is removed from the filtrate under reduced pressure. The residue is purified with a flash column chromatography (EtOAc-hexane) to give the desired product.

References


PubMed Literature


TCIMAIL
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