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CAS RN: 434-45-7 | Product Number: T0848
2,2,2-Trifluoroacetophenone
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Purity: >98.0%(GC)
Synonyms:
Product Documents:
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| 5G |
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24 | ≥100 | Contact Us | |
| 25G |
$114.00
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| Product Number | T0848 |
| Purity / Analysis Method | >98.0%(GC) |
| Molecular Formula / Molecular Weight | C__8H__5F__3O = 174.12 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 434-45-7 |
| Reaxys Registry Number | 1866286 |
| PubChem Substance ID | 87576681 |
| SDBS (AIST Spectral DB) | 10872 |
| MDL Number | MFCD00000420 |
Specifications
| Appearance | Colorless to Light yellow to Light orange clear liquid |
| Purity(GC) | min. 98.0 % |
Properties (reference)
| Boiling Point | 166 °C |
| Flash point | 41 °C |
| Specific Gravity (20/20) | 1.28 |
| Refractive Index | 1.46 |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H226 : Flammable liquid and vapor. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P403 + P235 : Store in a well-ventilated place. Keep cool. |
Related Laws:
Transport Information:
| UN Number | UN1224 |
| Class | 3 |
| Packing Group | III |
| H.S.code* | 2914.79-000 |
Application
An Epoxidation of Alkenes using H2O2 (aq.) and 2,2,2-Trifluoroacetophenone
Typical Procedure (Entry 1): 1-Phenyl-1-cyclohexene (158 mg, 1.0 mmol) is placed in a round-bottom flask followed by 2,2,2-trifluoroacetophenone (9.0 mg, 0.05 mmol). tert-Butyl alcohol (1.5 mL), aqueous buffer solution (1.5 mL, 0.6 M K2CO3, 4×10－5 M EDTA tetrasodium salt), acetonitrile (0.11 mL, 2.0 mmol), and 30% aqueous H2O2 (0.23 mL, 2.0 mmol) are added consecutively. The reaction mixture is allowed to stir for 1 h at room temperature. The crude product is purified using flash column chromatography to afford 1-phenyl-7-oxabicyclo[4.1.0]heptane (173 mg, yield 99%) as a colorless oil.
References
PubMed Literature
Articles/Brochures
TCIMAIL
[Research Articles] An Epoxidation of Alkenes using H2O2 (aq.) and 2,2,2-TrifluoroacetophenoneProduct Documents (Note: Some products will not have analytical charts available.)
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