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CAS RN: 1271-66-5 | Product Number: D4100
Dimethyltitanocene (5% in Tetrahydrofuran/Toluene)
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Purity:
Synonyms:
- Bis(cyclopentadienyl)dimethyltitanium (5% in Tetrahydrofuran/Toluene)
- Petasis Reagent (5% in Tetrahydrofuran/Toluene)
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days |
|---|---|---|---|
| 25G |
$103.00
|
≥40 | 5 |
| 100G |
$292.00
|
32 | 3 |
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to order our products. The above prices do not include freight cost, customs, and other charges to the destination.
* The storage conditions are subject to change without notice.
| Product Number | D4100 |
| Molecular Formula / Molecular Weight | C__1__2H__1__6Ti = 208.13 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Frozen (<0°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive,Heat Sensitive |
| CAS RN | 1271-66-5 |
| Reaxys Registry Number | 14221496 |
| PubChem Substance ID | 135727045 |
| MDL Number | MFCD02093882 |
Specifications
| Appearance | Orange to Red clear liquid |
| Concentration(HNMR) | 5.0 to 5.7 w/w% |
| NMR | confirm to structure |
Properties (reference)
| Specific Gravity (20/20) | 0.89 |
| Refractive Index | 1.49 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H332 : Harmful if inhaled. H315 : Causes skin irritation. H319 : Causes serious eye irritation. H360 : May damage fertility or the unborn child. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H351 : Suspected of causing cancer. H335 : May cause respiratory irritation. H336 : May cause drowsiness or dizziness. H304 : May be fatal if swallowed and enters airways. H401 : Toxic to aquatic life. H225 : Highly flammable liquid and vapor. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P201 : Obtain special instructions before use. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P331 : Do NOT induce vomiting. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number | UN1993 |
| Class | 3 |
| Packing Group | II |
| H.S.code* | 3822.19-000 |
Application
Methylenations of Carbonyl Compounds
References
- N. A. Petasis, E. I. Bzowej, J. Am. Chem. Soc. 1990, 112, 6392.
- N. A. Petasis, S.-P. Lu, E. I. Bzowej, D.-K. Fu, J. P. Staszewski, I. Akritopoulou-Zanze, M. A. Patane, Y.-H. Hu, Pure Appl. Chem. 1996, 68, 667.
Application
Ring-Closing Metathesis Using Petasis Reagent
Reference
- Olefin Metathesis in Cyclic Ether Formation. Direct Conversion of Olefinic Esters to Cyclic Enol Ethers with Tebbe-Type Reagents
PubMed Literature
Articles/Brochures
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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