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CAS RN: 130004-33-0 | Product Number: R0147
[RuCl(p-cymene)((S)-binap)]Cl
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![[RuCl(p-cymene)((S)-binap)]Cl](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "[RuCl(p-cymene)((S)-binap)]Cl")
Purity: >90.0%(HPLC)
Synonyms:
- Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 200MG |
$44.00
|
Contact Us | Contact Us | 10 |
|
| 1G |
$151.00
|
1 | 1 | 14 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
Supplemental Product Information:
This product was merchandised under the technical tie-up with TAKASAGO INTERNATIONAL CORPORATION.
We offer this product only in quantities for laboratory use.
| Product Number | R0147 |
| Purity / Analysis Method | >90.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__5__4H__4__6Cl__2P__2Ru = 928.88 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 130004-33-0 |
| Reaxys Registry Number | 16702130 |
| PubChem Substance ID | 253662112 |
| MDL Number | MFCD00134456 |
Specifications
| Appearance | White to Brown to Dark purple powder to crystal |
| Purity(HPLC) | min. 90 area% |
Properties (reference)
| Solubility in water | Insoluble |
GHS
Related Laws:
Transport Information:
| HS Number | 2843.90.0000 |
Application
An efficient ruthenium catalyst usable for high enatioselective hydrogenation of ketones
References
- Homogeneous asymmetric hydrogenation of o-chloroacetophenone to enantiomerically pure o -chloro-(1-phenyl)ethanol catalyzed by BINAP-Ru(II) complex
- Cationic BINAP-Ru(II) Halide Complexes: Highly Efficient Catalysts for Stereoselective Asymmetric Hydrogenation of .alpha.- and .beta.-Functionalized Ketones
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