Make sure to sign up for an account today for exclusive coupons and free shipping on orders over $75!
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 60871-84-3 | Product Number: N0861
Nickel(II) Trifluoromethanesulfonate
×
![]()
×
Purity: >96.0%(T)
Synonyms:
- Trifluoromethanesulfonic Acid Nickel(II) Salt
- Nickel(II) Triflate
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 1G |
$36.00
|
Contact Us | 1 | 23 |
|
| 5G |
$123.00
|
4 | 2 | ≥100 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | N0861 |
| Purity / Analysis Method | >96.0%(T) |
| Molecular Formula / Molecular Weight | C__2F__6NiO__6S__2 = 356.82 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 60871-84-3 |
| Reaxys Registry Number | 10590495 |
| PubChem Substance ID | 125307294 |
| MDL Number | MFCD00673740 |
Specifications
| Appearance | Light yellow to Yellow to Green powder to crystal |
| Purity(Chelometric Titration) | min. 96.0 % |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H314 : Causes severe skin burns and eye damage. H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 : May cause cancer. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P285 : In case of inadequate ventilation wear respiratory protection. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P272 : Contaminated work clothing must not be allowed out of the workplace. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P363 : Wash contaminated clothing before reuse. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
Related Laws:
Transport Information:
| UN Number (DOT-AIR) | UN1759 |
| Class (DOT-AIR) | 8 |
| Packing Group (TCI-A) | III |
| HS Number | 2904.10.5000 |
Application
8-アミノキノリン部位を持つ芳香族アミドのC―H結合直接アリール化反応
Typical Procedure (Entry 1):
In an oven-dried 5 mL screw-capped vial in a glovebox, 2-methyl-N-(8-quinolinyl)benzamide (79 mg, 0.3 mmol), iodobenzene (122 mg, 0.6 mmol), Ni(OTf)2 (5 mg, 0.015 mmol), NaHCO3 (50 mg, 0.6 mmol), and toluene (1 mL) are added. The mixture is stirred for 20 h at 160 °C followed by cooling. The mixture is filtered through a Celite pad and concentrated in vacuo. The residue is purified by column chromatography on silica gel (hexane : EtOAc = 10 : 1) to afford the desired arylated product (97 mg, Y. 94%) as a colorless oil.
In an oven-dried 5 mL screw-capped vial in a glovebox, 2-methyl-N-(8-quinolinyl)benzamide (79 mg, 0.3 mmol), iodobenzene (122 mg, 0.6 mmol), Ni(OTf)2 (5 mg, 0.015 mmol), NaHCO3 (50 mg, 0.6 mmol), and toluene (1 mL) are added. The mixture is stirred for 20 h at 160 °C followed by cooling. The mixture is filtered through a Celite pad and concentrated in vacuo. The residue is purified by column chromatography on silica gel (hexane : EtOAc = 10 : 1) to afford the desired arylated product (97 mg, Y. 94%) as a colorless oil.
References
PubMed Literature
Articles/Brochures
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.