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CAS RN: 19232-03-2 | Product Number: D5369
Dichlorobis(dicyclohexylphenylphosphine)nickel(II)
×
Purity: >95.0%(T)
Synonyms:
- Bis(dicyclohexylphenylphosphino)nickel(II) Dichloride
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
Shipping Information
|
|---|---|---|---|---|---|---|
| 250MG |
$67.00
|
1 | 2 | 14 |
|
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| Product Number | D5369 |
Purity / Analysis Method 
|
>95.0%(T) |
| Molecular Formula / Molecular Weight | C__3__6H__5__4Cl__2NiP__2 = 678.37 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature
|
Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 19232-03-2 |
| Reaxys Registry Number | 11423670 |
| PubChem Substance ID | 468591333 |
| MDL Number | MFCD25563227 |
Specifications
| Appearance | Orange to Brown to Dark purple powder to crystal |
| Purity(Chelometric Titration) | min. 95.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H372 : Causes damage to organs through prolonged or repeated exposure. H317 : May cause an allergic skin reaction. H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 : May cause cancer. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dust. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P285 : In case of inadequate ventilation wear respiratory protection. P201 : Obtain special instructions before use. P264 : Wash skin thoroughly after handling. P272 : Contaminated work clothing must not be allowed out of the workplace. P280: Wear protective gloves, protective clothing, eye protection and face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P342 + P311 : If experiencing respiratory symptoms: Call a POISON CENTER/doctor. P308 + P313 : IF exposed or concerned: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash it before reuse. P304 + P340 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. P333 + P313 : If skin irritation or rash occurs: Get medical advice/ attention. P405 : Store locked up. |
Related Laws:
Transport Information:
| HS Number | 2931.59.0080 |
Application
Nickel Complexes for the Cross-Coupling Reactions Using Alkoxy Groups as Leaving Groups
References
- Activation of Grignard reagents by transition-metal complexes. A new and simple synthesis of trans-stilbenes and polyphenyls
- Selective carbon-carbon bond formation by cross-coupling of Grignard reagents with organic halides. Catalysis by nickel-phosphine complexes
- Nickel-Catalyzed Cross-Coupling of Aryl Grignard Reagents with Aromatic Alkyl Ethers: An Efficient Synthesis of Unsymmetrical Biaryls
Application
Cross-Coupling Reaction of Aryl Grignard Reagents with Aryl Alkyl Ethers
References
- Nickel-Catalyzed Cross-Coupling of Aryl Grignard Reagents with Aromatic Alkyl Ethers: An Efficient Synthesis of Unsymmetrical Biaryls
Product Articles
[Product Highlights] Nickel Complexes for the Cross-Coupling Reactions Using Alkoxy Groups as Leaving GroupsProduct Documents (Note: Some products will not have analytical charts available.)
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Specifications
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