Make sure to sign up for an account today for exclusive coupons and free shipping on orders over $75!
Maximum quantity allowed is 999
Please select the quantity
CAS RN: 104-92-7 | Product Number: B0547
4-Bromoanisole
×
![]()
×
Purity: >97.0%(GC)
Synonyms:
- 1-Bromo-4-methoxybenzene
Product Documents:
| Size | Unit Price | Philadelphia, PA | Portland, OR | Japan* | Quantity |
|---|---|---|---|---|---|
| 25G |
$18.00
|
6 | 2 | ≥100 |
|
| 100G |
$34.00
|
5 | 1 | ≥40 |
|
| 500G |
$101.00
|
2 | 2 | 37 |
|
* Items in stock locally ship in 1-2 business days. Items from Japan stock are able to ship from a US warehouse within 2 weeks. Please contact TCI for lead times on items not in stock. Excludes regulated items and items that ship on ice.
* To send your quote request for bulk quantities, please click on the "Request Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | B0547 |
| Purity / Analysis Method | >97.0%(GC) |
| Molecular Formula / Molecular Weight | C__7H__7BrO = 187.04 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 104-92-7 |
| Reaxys Registry Number | 1237590 |
| PubChem Substance ID | 87563566 |
| SDBS (AIST Spectral DB) | 1722 |
| Merck Index (14) | 1428 |
| MDL Number | MFCD00000097 |
Specifications
| Appearance | Colorless to Almost colorless clear liquid |
| Purity(GC) | min. 97.0 % |
Properties (reference)
| Melting Point | 12 °C |
| Boiling Point | 215 °C |
| Flash point | 94 °C |
| Specific Gravity (20/20) | 1.50 |
| Refractive Index | 1.56 |
GHS
Related Laws:
| RTECS# | BZ8501000 |
Transport Information:
| HS Number | 2909.30.6000 |
Application
Introduction of a (pinacolatoboryl)methyl group into aromatic rings
To a solution of bis(pinacolatoboryl)methane (B4103, 80 mg, 0.3 mmol, 2 eq.), 4-bromoanisole (B0547, 27.9 mg, 0.149 mmol), and Pd[P(t-Bu)3]2(B3161, 3.8 mg, 7.4 µmol, 5 mol%) in dioxane 1.5 mL is added 8 N KOH aq. (37 µL, 0.3 mmol, 2 eq.) at room temperature. The mixture is stirred at 25 °C for 1 h and filtered through a pad of silica gel with ether. Concentration gives the residue, and purification by silica gel column chromatography (hexane/EtOAc = 10/1) gives the product in 92% yield.
References
- Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of Benzylboronates
PubMed Literature
Product Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
Please select Language.
The requested SDS is not available.
Please Contact Us for more information.
Specifications
C of A & Other Certificates
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
Sample C of A
This is a sample C of A and may not represent a recently manufactured lot of the product.
A sample C of A for this product is not available at this time.
Analytical Charts
Please enter Lot Number
Incorrect Lot Number. Please input only the 4-5 alphanumeric characters before the hyphen.
The requested analytical chart is not available. Sorry for the inconvenience.