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Dess-Martin Oxidation

Dess-Martin oxidation is a mild synthetic method used to convert primary and secondary alcohols to aldehydes and ketones respectively. The principle compound used for this oxidation is Dess-Martin periodinane (DMP), which can be prepared by two-step synthesis from 2-iodobenzoic acid. Dess-Martin oxidation has several advantages over classic Cr(VI)-based oxidation methods including mild conditions, expanded substrate tolerance, reduced environmental impact, and easy handling and workup. Dess-Martin Oxidation is widely used in organic synthesis, including late-stage total synthesis due to the mild nature of the conditions.
Reagents:
Dess-Martin periodinane
Reactants:
Alcohols
Products:
Aldehydes, Ketones
Scheme:

Dess-Martin Oxidation

Original literature:
Review literature:

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