Maximum quantity allowed is 999
CAS RN: 26628-22-8 | 제품번호: S0489
Sodium Azide

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Appearance | White to Almost white powder to crystaline |
Purity(Cerium redox Method) | min. 99.0 % |
Solubility in water | Soluble |
Degree of solubility in water | 417 g/l 17 °C |
용해성 (미세 용접) | Ethanol |
용해도 (불용성) | Ether |
픽토그램 |
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신호 워드 | Danger |
위험물 및 유해 등록 | H300 + H310 : Fatal if swallowed or in contact with skin. H314 : Causes severe skin burns and eye damage. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H373 : May cause damage to organs through prolonged or repeated exposure. H410 : Very toxic to aquatic life with long lasting effects. |
주의 사항 | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P262 : Do not get in eyes, on skin, or on clothing. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P391 : Collect spillage. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P361 + P364 : Take off immediately all contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P310 + P330 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P405 : Store locked up. |
RTECS # | JY8050000 |
UN 번호 | UN1687 |
등급 | 6.1 |
포장 그룹 | II |
HS 번호* | 2850.00-000 |
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Used Chemicals
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Procedure
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Sodium azide (139 mg, 2.14 mmol, 1.3 eq.) in toluene (3 mL) was added to a solution of 4-bromobenzonitrile (300 mg, 1.65 mmol) and triethylamine hydrochloride (295 mg, 2.14 mmol, 1.3 eq.) at room temperature. The mixture was stirred at 100 °C for 4 hours. Triethylamine hydrochloride (295 mg, 2.14 mmol, 1.3 eq.) and sodium azide (139 mg, 2.14 mmol, 1.3 eq.) were added and stirred overnight at the same temperature. Then the reaction mixture was quenched with water (15 mL) and the aqueous layer was washed with ethyl acetate (15 mL x 2) and was removed under reduced pressure and the residue was purified by column chromatography (on silica gel, dichloromethane:methanol = 5:1) and washed with acetonitrile:water (1:1, 6 mL) to give 5-(4-bromophenyl)-1H-tetrazole as a white solid (240 mg, 65% yield).
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Experimenter’s Comments
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The reaction mixture was monitored by UPLC.
The reaction was performed in a fume hood because hydrogen azide may be generated.
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Analytical Data
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5-(4-Bromophenyl)-1H-tetrazole
1H NMR (400 MHz, CDCl3); δ 7.99 (d, J = 8.0 Hz, 2H), 7.84 (d, J = 8.0 Hz, 2H).
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Lead Reference
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- (S)-5-PYRROLIDIN-2-YL-1H-TETRAZOLE
References
SDS
요청한 SDS를 사용할 수 없습니다.
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규격표
시험성적서, 각종 증명서
샘플 시험성적서
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분석 차트
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