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CAS RN: 2893755-25-2 | Product Number: D5513
1,3-Di-tert-butylimidazolium Hydrogencarbonate (contains varying amounts of 1,3-Di-tert-butylimidazolium-2-carboxylate)
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Purity: >98.0%(HPLC)
Synonyms:
- [ItBu(H)][HCO3] (contains varying amounts of 1,3-Di-tert-butylimidazolium-2-carboxylate)
Product Documents:
| Size | Unit Price | Same Day | 2-3 Business Days | Other Lead Time |
Shipping Information
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|---|---|---|---|---|---|
| 1G |
₩227,600
|
≥40 | 0 | Contact Us |
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* The storage conditions are subject to change without notice.
* The storage conditions are subject to change without notice.
| Product Number | D5513 |
| Purity / Analysis Method | >98.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__1__2H__2__2N__2O__3 = 242.32 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Moisture Sensitive |
| Packaging and Container | 1G-Glass Bottle with Plastic Insert (View image) |
| CAS RN | 2893755-25-2 |
| Related CAS RN | 479641-76-4 |
| Reaxys Registry Number | 19785611 |
| PubChem Substance ID | 354335709 |
Specifications
| Appearance | White to Light yellow powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| Purity(Nonaqueous Titration) | min. 95.0 % |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
Related Laws:
Transport Information:
| H.S.code* | 2933.29-000 |
Application
NHC Hydrogencarbonate Salts: Transition metal / NHC complex catalyst preparation
(CH3)2SAuCl (11.4 mg), NHC hydrogen carbonate salt (1.2 eq.), and THF (0.7 mL) are put in a capped vial (air atmosphere). After 1 h of stirring at 50 °C, the solution is filtered over silica and dried in vacuo. The Au-NHC complex is obtained as a colorless solid in 95% yield.
References
- Imidazol(in)ium Hydrogen Carbonates as a Genuine Source of N-Heterocyclic Carbenes (NHCs): Applications to the Facile Preparation of NHC Metal Complexes and to NHC-Organocatalyzed Molecular and Macromolecular Syntheses
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