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DIANANE-Salen Ligand - for Asymmetric Nozaki-Hiyama-Kishi Reaction -

No.128(March 2008)
B2652
(1R,2R,4R,5R)-2,5-Bis(3,5-di-tert-butyl-2-hydroxybenzylideneamino)bicyclo[2.2.1]heptane (1a)
B2653
(1S,2S,4S,5S)-2,5-Bis(3,5-di-tert-butyl-2-hydroxybenzylideneamino)bicyclo[2.2.1]heptane (1b)
DIANANE-Salen ligand 1 is a useful reagent for the asymmetric Nozaki-Hiyama-Kishi (NHK) reaction as a ligand for transition metal complexes. Such complexes can be used as highly enantioselective catalysts to obtain chiral secondary alcohols in high enantiopurity.

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