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CAS RN: 289706-46-3 | Product Number: T3597
4-[2,2,2-Trifluoro-1-[(trimethylsilyl)oxy]ethyl]morpholine
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![4-[2,2,2-Trifluoro-1-[(trimethylsilyl)oxy]ethyl]morpholine](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "4-[2,2,2-Trifluoro-1-[(trimethylsilyl)oxy]ethyl]morpholine")
Purity: >95.0%(GC)
Synonyms:
Product Documents:
| Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
Shipping Information
|
|---|---|---|---|---|---|
| 1G |
¥8,300
|
2 | It can be shipped from Saitama warehouse on the same day* | Contact Us | |
| 5G |
¥29,100
|
4 | It can be shipped from Saitama warehouse on the same day* | Contact Us |
* Available Stock: Prompt shipment (for products) in Saitama/Hyogo warehouse. Stock In Other WH: Shipment in about 2-3 Business Days from Saitama warehouse. Please contact us
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | T3597 |
| Purity / Analysis Method | >95.0%(GC) |
| Molecular Formula / Molecular Weight | C__9H__1__8F__3NO__2Si = 257.33 |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| CAS RN | 289706-46-3 |
| Reaxys Registry Number | 8622317 |
| PubChem Substance ID | 354335215 |
Specifications
| Appearance | Colorless to Almost colorless clear liquid |
| Purity(GC) | min. 95.0 % |
Properties (reference)
| Flash point | 78 °C |
| Refractive Index | 1.41 |
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. H227 : Combustible liquid. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P403 + P235 : Store in a well-ventilated place. Keep cool. |
Related Laws:
| Fire Defense Law | Group-4-3-III |
Transport Information:
Application
Morpholine Derivative Usable for Introduction of a Trifluoromethyl Group
Trifluoromethylation of Aryl Iodides2): A Schlenk tube is charged with CuI (0.030 mmol, 5.7 mg), 1,10-phenanthroline (0.030 mmol, 5.4 mg) and CsF (0.60 mmol, 67.3 mg). The tube is evacuated and backfilled with argon, and then diglyme (0.60 mL), 4-nitroiodobenzene (0.30 mmol, 74.7 mg), and 1 (0.60 mmol, 154 mg) are added. The resulting reaction mixture is stirred at 80 °C for 24 h. After the reaction is complete, the mixture is cooled to room temperature, diluted with water, and extracted with ethyl acetate. The combined organic layers are washed with brine, dried over MgSO4, filtered, and the volatiles are removed in vacuo. The residue is purified by chromatography on silica gel to yield 4-nitrobenzotrifluoride (77% yield).
References
- 1)New Stable Reagents for the Nucleophilic Trifluoromethylation. 1. Trifluoromethylation of Carbonyl Compounds with N-Formylmorpholine Derivatives
- 2)Copper-Catalyzed Aromatic Trifluoromethylation via Group Transfer from Fluoral Derivatives
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] Morpholine Derivative Usable for Introduction of a Trifluoromethyl GroupProduct Documents (Note: Some products will not have analytical charts available.)
Safety Data Sheet (SDS)
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Specifications
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