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CAS RN: 2950-43-8 | Product Number: H0530
Hydroxylamine-O-sulfonic Acid
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Purity: >90.0%(T)
Chemical Substance Law (ENCS):
2-4012
Synonyms:
- HSA
- HOSA
Product Documents:
| Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
Shipping Information
|
|---|---|---|---|---|---|
| 25G |
¥6,600
|
7 | It can be shipped from Saitama warehouse on the same day* | Contact Us | |
| 100G |
¥19,700
|
Contact Us | Contact Us | Contact Us | |
| 500G |
¥55,000
|
Contact Us | Contact Us | Contact Us |
* Available Stock: Prompt shipment (for products) in Saitama/Hyogo warehouse. Stock In Other WH: Shipment in about 2-3 Business Days from Saitama warehouse. Please contact us
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* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | H0530 |
| Purity / Analysis Method | >90.0%(T) |
| Molecular Formula / Molecular Weight | H__3NO__4S = 113.09 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Hygroscopic |
| CAS RN | 2950-43-8 |
| Reaxys Registry Number | 878303 |
| PubChem Substance ID | 87570919 |
| MDL Number | MFCD00011604 |
Specifications
| Appearance | White to Almost white powder to crystal |
| Purity(Iodometric Titration) | min. 90.0 % |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H302 + H312 + H332 : Harmful if swallowed, in contact with skin or if inhaled. H314 : Causes severe skin burns and eye damage. H290 : May be corrosive to metals. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P260 : Do not breathe dusts or mists. P270 : Do not eat, drink or smoke when using this product. P234 : Keep only in original container. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P390 : Absorb spillage to prevent material damage. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P301 + P330 + P331 : IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P301 + P312 + P330 : IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P304 + P340 + P310 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. P305 + P351 + P338 + P310 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P406 : Store in corrosive resistant container with a resistant inner liner. P405 : Store locked up. |
Related Laws:
| Chemical Substance Law (ENCS) |
2-4012 |
| RTECS# | NC5427000 |
Transport Information:
| UN Number | UN3261 |
| Class | 8 |
| Packing Group | III |
Application
Hydroxylamine for the Transition-Metal-Free Amination Reaction
Experimental procedure:
To the boronic acid (1.0 mmol) in MeCN (5 mL) is added HSA (170 mg, 1.5 eq.), followed by aq. NaOH solution (1 mol/L, 5 mL). The biphasic mixture is stirred for 16 h at room temperature. The reaction mixture is diluted with H2O (30 mL, saturated aq. NH4Cl for products containing acidic functional groups) and extracted with EtOAc (2 × 30 mL). The combined organic extracts are dried (Na2SO4) and concentrated in vacuo. The residue is purified by flash chromatography (EtOAc:hexanes) to afford the amine product.
References
- Transition-Metal-Free Access to Primary Anilines from Boronic Acids and a Common +NH2 Equivalent.
Application
Synthesis of N-H Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acid
References
- Direct and Stereospecific Synthesis of N-H and N-Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acids
PubMed Literature
Articles/Brochures
TCIMAIL
[Product Highlights] Hydroxylamine for the Transition-Metal-Free Amination Reaction[Product Highlights] Synthesis of N-H Aziridines from Unactivated Olefins Using Hydroxylamine-O-Sulfonic Acid
Product Documents (Note: Some products will not have analytical charts available.)
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Specifications
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