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CAS RN: 924-44-7 | Product Number: G0264
Ethyl Glyoxylate Polymer form (47% in Toluene)
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Purity:
Priority Assessment Chemical Substance
|Narcotic or Psychotropic Raw Material
Synonyms:
- Ethyl Oxoacetate Polymer form (47% in Toluene)
- Glyoxalic Acid Ethyl Ester Polymer form (47% in Toluene)
- Glyoxylic Acid Ethyl Ester Polymer form (47% in Toluene)
Product Documents:
| Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
Shipping Information
|
|---|---|---|---|---|---|
| 25G |
¥4,800
|
17 | 26 | 36 | |
| 100G |
¥14,400
|
2 | 25 | 13 | |
| 500G |
¥43,200
|
5 | 1 | Contact Us |
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* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | G0264 |
| Molecular Formula / Molecular Weight | (CH__3CH__2OCOCHO)__n |
| Physical State (20 deg.C) | Liquid |
| Storage Temperature | Refrigerated (0-10°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive,Heat Sensitive |
| CAS RN | 924-44-7 |
| Reaxys Registry Number | 1209486 |
| PubChem Substance ID | 87570438 |
| MDL Number | MFCD00044009 |
Specifications
| Appearance | Colorless to Almost colorlessclear liquid |
| Concentration(Oxime Formation) | 47.0 to 51.7 w/w% |
Properties (reference)
| Boiling Point | 110 °C |
| Flash point | 7 °C |
| Specific Gravity (20/20) | 1.03 |
| Refractive Index | 1.48 |
GHS
| Pictogram |
|
| Signal Word | Danger |
| Hazard Statements | H332 : Harmful if inhaled. H315 + H320 : Causes skin and eye irritation. H360 : May damage fertility or the unborn child. H370 : Causes damage to organs. H372 : Causes damage to organs through prolonged or repeated exposure. H341 : Suspected of causing genetic defects. H335 : May cause respiratory irritation. H336 : May cause drowsiness or dizziness. H304 : May be fatal if swallowed and enters airways. H401 : Toxic to aquatic life. H225 : Highly flammable liquid and vapor. |
| Precautionary Statements | P501 : Dispose of contents/ container to an approved waste disposal plant. P273 : Avoid release to the environment. P260 : Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P270 : Do not eat, drink or smoke when using this product. P202 : Do not handle until all safety precautions have been read and understood. P240 : Ground/bond container and receiving equipment. P210 : Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 : Keep container tightly closed. P201 : Obtain special instructions before use. P243 : Take precautionary measures against static discharge. P241 : Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 : Use only non-sparking tools. P271 : Use only outdoors or in a well-ventilated area. P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ protective clothing/ eye protection/ face protection. P370 + P378 : In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. P331 : Do NOT induce vomiting. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P311 : IF exposed or concerned: Call a POISON CENTER/doctor. P362 + P364 : Take off contaminated clothing and wash it before reuse. P303 + P361 + P353 : IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P301 + P310 : IF SWALLOWED: Immediately call a POISON CENTER/doctor. P304 + P340 + P312 : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P403 + P233 : Store in a well-ventilated place. Keep container tightly closed. P403 + P235 : Store in a well-ventilated place. Keep cool. P405 : Store locked up. |
Related Laws:
| Chemical Substance Law (ENCS) | Priority Assessment Chemical Substance |
| ISHL |
Organic Solvents Class 2 Mutagens |
| Narcotics and Psychotropics Control Law | Narcotic or Psychotropic Raw Material |
| PRTR Law (New Specific Chemical) | Class 1 Designated Chemical Substances |
| Fire Defense Law | Group-4-1-II |
Transport Information:
| UN Number | UN1294 |
| Class | 3 |
| Packing Group | II |
Application
Preparation of Monomeric Ethyl Glyoxylate
Polymeric ethyl glyoxylate toluene solution (30 g) was added to the flame dried flask. Toluene was evaporated completely under vacuum (less than 1 mmHg) at room temperature, and phosphorus pentoxide (ca. 300 mg) was added to the polymeric ethyl glyoxylate. The mixture was distilled to give almost-toluene-free monomeric ethyl glyoxylate as a slightly yellow liquid (150 mmHg, 80 °C). Monomeric ethyl glyoxylate easily polymerizes within 30 min to give viscous liquid. Therefore, distilled ethyl glyoxylate should be used immediately after purification.
References
PubMed Literature
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