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CAS RN: 92220-65-0 | Product Number: D5744
Dichlorotetrakis[2-(2-pyridinyl)phenyl]diiridium(III)
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![Dichlorotetrakis[2-(2-pyridinyl)phenyl]diiridium(III)](/_ui/responsive/theme-tci/images/missing_product_zoom.jpg "Dichlorotetrakis[2-(2-pyridinyl)phenyl]diiridium(III)")
Purity: >98.0%(HPLC)
Synonyms:
- [(ppy)2IrCl]2
Product Documents:
| Size | Unit Price | Saitama (Kawaguchi) | Hyogo (Amagasaki) | Stock in other WH |
Shipping Information
|
|---|---|---|---|---|---|
| 200MG |
¥13,800
|
18 | It can be shipped from Saitama warehouse on the same day* | Contact Us | |
| 1G |
¥48,400
|
4 | It can be shipped from Saitama warehouse on the same day* | Contact Us |
* Available Stock: Prompt shipment (for products) in Saitama/Hyogo warehouse. Stock In Other WH: Shipment in about 2-3 Business Days from Saitama warehouse. Please contact us
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*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
* The displayed price is the unit price and does not include consumption tax. The unit prices displayed are the latest and are subject to change without notice.
* To send your quote request for bulk quantities, please click on the "Request Bulk Quote" button. Please note that we cannot offer bulk quantities for some products.
*TCI frequently reviews storage conditions to optimize them. Please note that the latest information on the storage temperature for the products is described on our website.
| Product Number | D5744 |
| Purity / Analysis Method | >98.0%(HPLC) |
| Molecular Formula / Molecular Weight | C__4__4H__3__2Cl__2Ir__2N__4 = 1,072.10 |
| Physical State (20 deg.C) | Solid |
| Storage Temperature | Room Temperature (Recommended in a cool and dark place, <15°C) |
| Store Under Inert Gas | Store under inert gas |
| Condition to Avoid | Air Sensitive |
| CAS RN | 92220-65-0 |
| Reaxys Registry Number | 17830671 |
| PubChem Substance ID | 468591535 |
| MDL Number | MFCD07784515 |
Specifications
| Appearance | Light orange to Yellow to Green powder to crystal |
| Purity(HPLC) | min. 98.0 area% |
| NMR | confirm to structure |
Properties (reference)
GHS
| Pictogram |
|
| Signal Word | Warning |
| Hazard Statements | H315 : Causes skin irritation. H319 : Causes serious eye irritation. |
| Precautionary Statements | P264 : Wash skin thoroughly after handling. P280 : Wear protective gloves/ eye protection/ face protection. P302 + P352 : IF ON SKIN: Wash with plenty of water. P337 + P313 : If eye irritation persists: Get medical advice/ attention. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362 + P364 : Take off contaminated clothing and wash it before reuse. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. |
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Application
Preparing for Iridium-Organic Unit of Photoredox-active MOF
A mixture of H2dcbpy [B3502] (2 mmol, 0.5 g) and Ir2(ppy)4Cl2 [D5744] (1 mmol, 1 g) is dissolved in CH3OH (100 mL). Excessive Na2CO3 is added to the reaction mixture and then heated to reflux under stirring for 5 h. After cooling to room temperature, the solvent is removed under rotary evaporation. Deionized water is added to dissolve the precipitation by stirring, and the complex is achieved by the addition of hydrochloric acid, and then filtered and dried (82% yield based on Ir).
References
- A Dynamic Entangled Framework Based on an Iridium-Organic Unit Showing Reversible Luminescence Turn-on Sensing
Product Documents (Note: Some products will not have analytical charts available.)
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